Complete list from the university bibliography

Anzahl der Treffer: 485
Erstellt: Wed, 24 Apr 2024 23:17:36 +0200 in 0.0704 sec


Qian, Yudan; Zhou, Zhiming; Zhang, Qingcheng; Zhao, Huaping; Chen, Heng; Han, Jintong; Wan, Haiting; Jin, Huile; Wang, Shun; Lei, Yong
Boosting the energy density of bowl-like MnO2carbon through lithium-intercalation in a high-voltage asymmetric supercapacitor with “water-in-salt” electrolyte. - In: Small, ISSN 1613-6829, Bd. 0 (2024), 0, 2310037, S. 1-11

Highly concentrated “‘water-in-salt”’ (WIS) electrolytes are promising for high-performance energy storage devices due to their wide electrochemical stability window. However, the energy storage mechanism of MnO2 in WIS electrolytes-based supercapacitors remains unclear. Herein, MnO2 nanoflowers are successfully grown on mesoporous bowl-like carbon (MBC) particles to generate MnO2/MBC composites, which not only increase electroactive sites and inhibit the pulverization of MnO2 particles during the fast charging/discharging processes, but also facilitate the electron transfer and ion diffusion within the whole electrode, resulting in significant enhancement of the electrochemical performance. An asymmetric supercapacitor, assembled with MnO2/MBC and activated carbon (AC) and using 21 m LiTFSI solution as the WIS electrolyte, delivers an ultrahigh energy density of 70.2 Wh kg−1 at 700 W kg−1, and still retains 24.8 Wh kg−1 when the power density is increased to 28 kW kg−1. The ex situ XRD, Raman, and XPS measurements reveal that a reversible reaction of MnO2 + xLi+ + xe−↔LixMnO2 takes place during charging and discharging. Therefore, the asymmetric MnO2/MBC//AC supercapacitor with LiTFSI electrolyte is actually a lithium-ion hybrid supercapacitor, which can greatly boost the energy density of the assembled device and expand the voltage window.



https://doi.org/10.1002/smll.202310037
Nikiruy, Kristina; Perez, Eduardo; Baroni, Andrea; Reddy, Keerthi Dorai Swamy; Pechmann, Stefan; Wenger, Christian; Ziegler, Martin
Blooming and pruning: learning from mistakes with memristive synapses. - In: Scientific reports, ISSN 2045-2322, Bd. 14 (2024), 7802, S. 1-11

Blooming and pruning is one of the most important developmental mechanisms of the biological brain in the first years of life, enabling it to adapt its network structure to the demands of the environment. The mechanism is thought to be fundamental for the development of cognitive skills. Inspired by this, Chialvo and Bak proposed in 1999 a learning scheme that learns from mistakes by eliminating from the initial surplus of synaptic connections those that lead to an undesirable outcome. Here, this idea is implemented in a neuromorphic circuit scheme using CMOS integrated HfO2-based memristive devices. The implemented two-layer neural network learns in a self-organized manner without positive reinforcement and exploits the inherent variability of the memristive devices. This approach provides hardware, local, and energy-efficient learning. A combined experimental and simulation-based parameter study is presented to find the relevant system and device parameters leading to a compact and robust memristive neuromorphic circuit that can handle association tasks.



https://doi.org/10.1038/s41598-024-57660-4
Korder, Kristina; Cao, Hao; Salomons, Elad; Ostfeld, Avi; Li, Pu
Simultaneous minimization of water age and pressure in water distribution systems by pressure reducing valves. - In: Water resources management, ISSN 1573-1650, Bd. 0 (2024), 0, insges. 19 S.

Pressure reducing valves (PRVs) are essentially used to reduce operational pressures in water distribution systems (WDSs) to minimize water leakage. However, water age in a WDS is an important variable describing the water quality and should be kept as low as possible. Therefore, the aim of this study is to investigate the possibility and potential of simultaneously minimizing both pressure and water age by using PRVs. To determine the optimal location and setting of PRVs, a mixed-integer nonlinear programming (MINLP) problem is formulated with minimization of the sum of the weighted total water age and pressure as the objective function, where the weighting factor can be defined by the user’s preference. The equality constraints consist of the hydraulic equations and water age functions to describe pressure and water age in the distribution network, while the inequality constraints ensure them in the defined operating ranges, respectively. Applying the proposed approach to two case studies, the results show that both water age and pressure can indeed be significantly reduced by the optimized position and setting of the PRVs.



https://doi.org/10.1007/s11269-024-03828-6
Hannappel, Thomas; Shekarabi, Sahar; Jaegermann, Wolfram; Runge, Erich; Hofmann, Jan Philipp; Krol, Roel van de; May, Matthias M.; Paszuk, Agnieszka; Hess, Franziska; Bergmann, Arno; Bund, Andreas; Cierpka, Christian; Dreßler, Christian; Dionigi, Fabio; Friedrich, Dennis; Favaro, Marco; Krischok, Stefan; Kurniawan, Mario; Lüdge, Kathy; Lei, Yong; Roldán Cuenya, Beatriz; Schaaf, Peter; Schmidt-Grund, Rüdiger; Schmidt, W. Gero; Strasser, Peter; Unger, Eva; Montoya, Manuel Vasquez; Wang, Dong; Zhang, Hongbin
Integration of multi-junction absorbers and catalysts for efficient solar-driven artificial leaf structures : a physical and materials science perspective. - In: Solar RRL, ISSN 2367-198X, Bd. 0 (2024), 0, S. 1-88

Artificial leaves could be the breakthrough technology to overcome the limitations of storage and mobility through the synthesis of chemical fuels from sunlight, which will be an essential component of a sustainable future energy system. However, the realization of efficient solar-driven artificial leaf structures requires integrated specialized materials such as semiconductor absorbers, catalysts, interfacial passivation, and contact layers. To date, no competitive system has emerged due to a lack of scientific understanding, knowledge-based design rules, and scalable engineering strategies. Here, we will discuss competitive artificial leaf devices for water splitting, focusing on multi-absorber structures to achieve solar-to-hydrogen conversion efficiencies exceeding 15%. A key challenge is integrating photovoltaic and electrochemical functionalities in a single device. Additionally, optimal electrocatalysts for intermittent operation at photocurrent densities of 10-20 mA cm^-2 must be immobilized on the absorbers with specifically designed interfacial passivation and contact layers, so-called buried junctions. This minimizes voltage and current losses and prevents corrosive side reactions. Key challenges include understanding elementary steps, identifying suitable materials, and developing synthesis and processing techniques for all integrated components. This is crucial for efficient, robust, and scalable devices. Here, we discuss and report on corresponding research efforts to produce green hydrogen with unassisted solar-driven (photo-)electrochemical devices. This article is protected by copyright. All rights reserved.



https://doi.org/10.1002/solr.202301047
Philipp, Friedrich; Schaller, Manuel; Worthmann, Karl; Peitz, Sebastian; Nüske, Feliks
Error bounds for kernel-based approximations of the Koopman operator. - In: Applied and computational harmonic analysis, ISSN 1096-603X, Bd. 71 (2024), 101657, S. 1-25

We consider the data-driven approximation of the Koopman operator for stochastic differential equations on reproducing kernel Hilbert spaces (RKHS). Our focus is on the estimation error if the data are collected from long-term ergodic simulations. We derive both an exact expression for the variance of the kernel cross-covariance operator, measured in the Hilbert-Schmidt norm, and probabilistic bounds for the finite-data estimation error. Moreover, we derive a bound on the prediction error of observables in the RKHS using a finite Mercer series expansion. Further, assuming Koopman-invariance of the RKHS, we provide bounds on the full approximation error. Numerical experiments using the Ornstein-Uhlenbeck process illustrate our results.



https://doi.org/10.1016/j.acha.2024.101657
Freisinger, Elena; McCarthy, Ian P.
What fails and when? : a process view of innovation failure. - In: Technovation, Bd. 133 (2024), 102995, S. 1-14

Research on innovation failure has proliferated lately but with little theoretical attention given to the diversity of the concept. Using process theorizing, we present a model and propositions to understand how a firm's anticipation and value toward failure depends on the type of failure (task versus outcome) and the phase (divergent versus convergent) and point (early versus later) ‘within’ the process that the failure occurs. Using the anticipation-value stances, we then present a typology of four modes of innovation failure that can arise ‘from’ task and outcomes failure in the innovation process. The four modes (and associated learning response) are unsolicited failures (prevent-alert-eliminate); hazardous failures (predict-modify-mitigate); fortuitous failures (probe-expose-extrapolate); and excursive failures (facilitate-analyze-harness). To help explain the ideas in our process model and typology, we use the well-known IDEO shopping cart innovation project as an illustrative example. Together, these contributions provide contingency oriented insights on how failure varies and journeys within and from the innovation process, which helps researchers and managers to better understand the related causes, effects and learning responses.



https://doi.org/10.1016/j.technovation.2024.102995
Zheng, Niannian; Luan, Xiaoli; Shardt, Yuri A. W.; Liu, Fei
Dynamic-controlled Bayesian network for process pattern modeling and optimization. - In: Industrial & engineering chemistry research, ISSN 1520-5045, Bd. 0 (2024), 0, S. 1-11

Capturing the current statistical features of a process and its dynamic evolution is important for controlling and monitoring its overall operational status. In terms of capturing the process dynamics, existing probabilistic latent-variable methods mostly consider autoregressive relationships, and thus, the causality from the control inputs to the pattern, or key hidden variable, remains unmodeled or implicit. To bridge this gap, a model structured by a newly designed dynamic-controlled Bayesian network (DCBN) is proposed in this paper for pattern modeling, especially pattern control and optimization. Significantly, the innovation and advantage of the DCBN lie in explicitly quantifying the impulse response of the pattern under control inputs. As well, the expectation-maximization algorithm is specially designed for learning the DCBN model. Finally, a new framework for pattern-based process control and optimization is presented in which online pattern filtering and control can be implemented. A case study on the combustion process from an industrial boiler illustrates the advantages of the proposed method in that it can capture the controlled dynamics of the process and achieve optimization by tracking the pattern set point or trajectory.



https://doi.org/10.1021/acs.iecr.3c04391
Pikushina, Alena; Centeno, Luis Fernando; Stehr, Uwe; Jacobs, Heiko O.; Hein, Matthias
Electrical lengths and phase constants of stretchable coplanar transmission lines at GHz frequencies. - In: Flexible and printed electronics, ISSN 2058-8585, Bd. 9 (2024), 1, 015005, S. 1-12

Elastic, bendable and stretchable electronics establish a new and promising area of multi-physics engineering for a variety of applications, e.g. on wearables or in complex-shaped machine parts. While the area of metamorphic electronics has been investigated comprehensively, the behavior at radio frequencies (RFs), especially in the GHz range, is much less well studied. The mechanical deformation of the soft substrates, for instance, due to stretching, changes the geometrical dimensions and the electrical properties of RF transmission lines. This effect could be desirable in some cases, e.g. for smart devices with shape-dependent transmission or radiation characteristics, or undesirable in other cases, e.g. in feed and distribution networks due to the variable electrical lengths and thus phase variations. This contribution describes the results of a systematic study of the broadband RF properties of coplanar transmission lines on Ecoflex® substrates, based on numerical simulations and experimental data. Two types of stretchable transmission line structures were studied: Meander- and circular ring-segmented lines. Modeling and simulation were performed combining a 2D circuit simulation software with electromagnetic full-wave simulations. The experimental part of the work included the fabrication of metamorphic substrates metallized with thin copper layers and systematic measurements of the electrical lengths and phase constants of coplanar waveguides in the frequency range from 1 to 5 GHz based on vector network analysis for different stretching levels. With the given substrate technology, we succeeded in demonstrating stretchability up to a level of 21%, while the theoretical limit is expected at 57%. The meander- and circular-shaped line structures revealed markedly different sensitivities to the stretching level, which was lower for circular structures compared to the meander structures by approximately a factor of three.



https://doi.org/10.1088/2058-8585/ad1efd
Petrich, Martin; Kletzin, Ulf
Practical fatigue strength diagrams for compression springs based on the FKM-guideline “Analytic Strength Assessment for Springs“. - In: International journal of fatigue, Bd. 183 (2024), 108273, S. 1-8

Metal springs are used extensively in technical products. The mathematical relationships and Goodman diagrams contained in the DIN EN 13906-1 standard form the essential basis for the design and calculation of cylindrical helical compression springs. They are used not only nationally, but internationally in the spring industry and by spring users. However, the diagrams are more than 50 years old and no longer reflect the current status of modern spring materials and spring manufacturing technologies. This results in great uncertainty for users of the standard, which currently has to be compensated by costly fatigue tests. In order to overcome the problems, the research project IGF 19693 aimed to renew the Goodman diagrams of the DIN EN 13906-1 standard in accordance with the state of spring technology. Therefore, the FKM guideline “Analytic Strength Assessment for Springs and Spring Elements“ was used to calculate permissible fatigue strength values for standard springs. Additionally, an extensive experimental program was carried out with fatigue tests on cold-formed helical compression springs to validate the calculations. The main results of the project are presented in this manuscript, which strengthens SMEs in designing competitive springs, which they can offer in a shorter time and at a lower cost due to lower development costs.



https://doi.org/10.1016/j.ijfatigue.2024.108273
Schwarz, Andreas; Unselt, Janina Jacqueline
Rage against the machine? : framing societal threat and efficacy in YouTube videos about artificial intelligence. - In: Risk analysis, ISSN 1539-6924, Bd. 0 (2024), 0, S. 1-19

Artificial intelligence (AI) has become a part of the mainstream public discourse beyond expert communities about its risks, benefits, and need for regulation. In particular, since 2014, the news media have intensified their coverage of this emerging technology and its potential impact on most domains of society. Although many studies have analyzed traditional media coverage of AI, analyses of social media, especially video-sharing platforms, are rare. In addition, research from a risk communication perspective remains scarce, despite the widely recognized potential threats to society from many AI applications. This study aims to detect recurring patterns of societal threat/efficacy in YouTube videos, analyze their main sources, and compare detected frames in terms of reach and response. Using a theoretical framework combining framing and risk communication, the study analyzed the societal threat/efficacy attributed to AI in easily accessible YouTube videos published in a year when public attention to AI temporarily peaked (2018). Four dominant AI frames were identified: the balanced frame, the high-efficacy frame, the high-threat frame, and the no-threat frame. The balanced and no-threat frames were the most prevalent, with predominantly positive and neutral AI narratives that neither adequately address the risks nor the necessary societal response from a normative risk communication perspective. The results revealed the specific risks and benefits of AI that are most frequently addressed. Video views and user engagement with AI videos were analyzed. Recommendations for effective AI risk communication and implications for risk governance were derived from the results.



https://doi.org/10.1111/risa.14299