Reducing reservoir computer hyperparameter dependence by external timescale tailoring. - In: Neuromorphic computing and engineering, ISSN 2634-4386, Bd. 4 (2024), 1, 014001, S. 1-16
Task specific hyperparameter tuning in reservoir computing is an open issue, and is of particular relevance for hardware implemented reservoirs. We investigate the influence of directly including externally controllable task specific timescales on the performance and hyperparameter sensitivity of reservoir computing approaches. We show that the need for hyperparameter optimisation can be reduced if timescales of the reservoir are tailored to the specific task. Our results are mainly relevant for temporal tasks requiring memory of past inputs, for example chaotic timeseries prediction. We consider various methods of including task specific timescales in the reservoir computing approach and demonstrate the universality of our message by looking at both time-multiplexed and spatially-multiplexed reservoir computing.
https://doi.org/10.1088/2634-4386/ad1d32
Indefinite Sturm-Liouville operators in polar form. - In: Integral equations and operator theory, ISSN 1420-8989, Bd. 96 (2024), 2, S. 1-58
https://doi.org/10.1007/s00020-023-02746-3
Experimental validation for the combination of funnel control with a feedforward control strategy. - In: Multibody system dynamics, ISSN 1573-272X, Bd. 0 (2024), 0, S. 1-19
Current engineering design trends, such as lightweight machines and human-machine interaction, often lead to underactuated systems. Output trajectory tracking of such systems is a challenging control problem. Here, we use a two-design-degree of freedom control approach by combining funnel feedback control with feedforward control based on servo-constraints. We present experimental results to verify the approach and demonstrate that the addition of a feedforward controller mitigates drawbacks of the funnel controller. We also present new experimental results for the real-time implementation of a feedforward controller based on servo-constraints on a minimum phase system.
https://doi.org/10.1007/s11044-024-09976-2
Infrared light dual excitation of Ni-phytate-sensitized ZnIn2S4 with sulfur vacancies for enhanced NIR-driven photocatalysis. - In: Chemical communications, ISSN 1364-548X, Bd. 60 (2024), 8, S. 1035-1038
Near-infrared (NIR) light accounts for about half of the solar spectrum, and the effective utilization of low-energy NIR light is an important but challenging task in the field of photocatalysis. Molecular semiconductor photocatalytic systems (MSPSs) are highly tunable, available and stable, and are considered to be one of the most promising ways to achieve efficient NIR hydrogen production. Here, we demonstrate efficient dual-excitation in MSPS consisting of ZnIn2S4−x (ZIS1−x) with sulfur vacancies and phytic acid nickel (PA-Ni), which differs from other NIR-responsive photosensitized systems. The system achieves a hydrogen evolution reaction (HER) of 119.85 μmol h−1 g−1 at λ > 800 nm illumination, which is an excellent performance among all reported NIR catalysts and even outperforms the noble metal catalysts when compared to the reported literature. The superior activity is attributed to the unique charge dynamics and higher carrier concentration of the system. This work demonstrates the potential of dual-excitation systems for efficient utilization of low-energy NIR light.
https://doi.org/10.1039/D3CC05089K
Ordered anodic aluminum oxide-based nanostructures for surface-enhanced Raman scattering: a review. - In: ACS applied nano materials, ISSN 2574-0970, Bd. 7 (2024), 1, S. 11-31
As a promising spectroscopic technique, surface enhanced raman spectroscopy (SERS) has been intensively used in bio/chemical sensing, attributing to its unique advantages of ultrasensitive and accurate detection of trace amounts of analytes, high specific fingerprint-like features, fast response, and noninvasive sensing. The robustness and consistency of SERS signals in practical analytical applications highly rely on the composition, structural morphology, and uniformity of SERS substrates. These factors play a pivotal role in determining the intensity and reproducibility of the detected signals. SERS substrates based on ordered nanostructures that are fabricated from anodic aluminum oxide (AAO)-template-assisted approaches are of significant interest due to their cost effectiveness, scalability, precise structural control, and exceptionally ordered features. In this review, recent progress in SERS substrates with high sensitivity and reproducibility prepared from AAO templates is highlighted. We emphasize the optimization strategies toward achieving efficient SERS-active substrates by fine-tuning the size, composition, and morphology of AAO-derived ordered nanostructures. Furthermore, we delve into the discussion of flexible and smart SERS substrates, while also exploring key aspects pertinent to further amplifying SERS signals. Overall, this review aims to offer insights into the future integration of the AAO templates technique with SERS, providing crucial perspectives for forthcoming research in this field.
https://doi.org/10.1021/acsanm.3c04652
Feedback rectifiable pairs and stabilization of switched linear systems. - In: Systems & control letters, ISSN 1872-7956, Bd. 186 (2024), 105755, S. 1-10
We address the feedback design problem for switched linear systems. In particular we aim to design a switched state-feedback such that the resulting closed-loop subsystems share the same eigenstructure. To this effect we formulate and analyse the feedback rectification problem for pairs of matrices. We present necessary and sufficient conditions for the feedback rectifiability of pairs for two subsystems and give a constructive procedure to design stabilizing state-feedback for a class of switched systems. In particular the proposed algorithm provides sets of eigenvalues and corresponding eigenvectors for the closed-loop subsystems that guarantee stability for arbitrary switching. Several examples illustrate the characteristics of the problem considered and the application of the proposed design procedure.
https://doi.org/10.1016/j.sysconle.2024.105755
Efficient analytical evaluation of the singular BEM integrals for the three-dimensional Laplace and Stokes equations over polygonal elements. - In: Engineering analysis with boundary elements, ISSN 0955-7997, Bd. 161 (2024), S. 70-77
Singularities in the fundamental solutions pose a mathematical challenge for all applications of the boundary element method, if the source and field point lie on the same element. To avoid complex and error-prone numerical procedures, analytical solutions for the integrals that arise are desirable. In this work, easy and efficiently to implement analytical solutions are presented for the fundamental solutions of the three-dimensional Stokes equation as well as Laplace’s equation. Explicit expressions are derived for general triangular elements using constant shape functions. In addition, options for extending to arbitrary polygonal elements are shown. In particular, the three cases that the incenter, the centroid or the vertices of the triangles are used as source points for the calculation are addressed. The impressive numerical efficiency of the method is demonstrated by explicit examples.
https://doi.org/10.1016/j.enganabound.2024.01.013
Insights into nano- and micro-structured scaffolds for advanced electrochemical energy storage. - In: Nano-Micro letters, ISSN 2150-5551, Bd. 16 (2024), 1, 130, S. 1-44
Adopting a nano- and micro-structuring approach to fully unleashing the genuine potential of electrode active material benefits in-depth understandings and research progress toward higher energy density electrochemical energy storage devices at all technology readiness levels. Due to various challenging issues, especially limited stability, nano- and micro-structured (NMS) electrodes undergo fast electrochemical performance degradation. The emerging NMS scaffold design is a pivotal aspect of many electrodes as it endows them with both robustness and electrochemical performance enhancement, even though it only occupies complementary and facilitating components for the main mechanism. However, extensive efforts are urgently needed toward optimizing the stereoscopic geometrical design of NMS scaffolds to minimize the volume ratio and maximize their functionality to fulfill the ever-increasing dependency and desire for energy power source supplies. This review will aim at highlighting these NMS scaffold design strategies, summarizing their corresponding strengths and challenges, and thereby outlining the potential solutions to resolve these challenges, design principles, and key perspectives for future research in this field. Therefore, this review will be one of the earliest reviews from this viewpoint.
https://doi.org/10.1007/s40820-024-01341-4
Enhancing the performance of quantum reservoir computing and solving the time-complexity problem by artificial memory restriction. - In: Physical review research, ISSN 2643-1564, Bd. 6 (2024), 1, 013051, S. 013051-1-013051-11
We propose a scheme that can enhance the performance and reduce the computational cost of quantum reservoir computing. Quantum reservoir computing is a computing approach which aims at utilizing the complexity and high dimensionality of small quantum systems, together with the fast trainability of reservoir computing, in order to solve complex tasks. The suitability of quantum reservoir computing for solving temporal tasks is hindered by the collapse of the quantum system when measurements are made. This leads to the erasure of the memory of the reservoir. Hence, for every output, the entire input signal is needed to reinitialize the reservoir, leading to quadratic time complexity. Another critical issue for the hardware implementation of quantum reservoir computing is the need for an experimentally accessible means of tuning the nonlinearity of the quantum reservoir. We present an approach which addresses both of these issues. We propose artificially restricting the memory of the quantum reservoir by only using a small number inputs to reinitialize the reservoir after measurements are performed. This strongly influences the nonlinearity of the reservoir response due to the influence of the initial reservoir state, while also substantially reducing the number of quantum operations needed to perform time-series prediction tasks due to the linear rather than quadratic time complexity. The reinitialization length therefore provides an experimental accessible means of tuning the nonlinearity of the response of the reservoir, which can lead to significant task-specific performance improvement. We numerically study the linear and quadratic algorithms for a fully connected transverse Ising model and a quantum processor model.
https://doi.org/10.1103/PhysRevResearch.6.013051
Research progress on vanadium sulfide anode materials for sodium and potassium-ion batteries. - In: Advanced Materials Technologies, ISSN 2365-709X, Bd. n/a (2024), n/a, 2301840, S. 1-28
Considering environmental changes and the demand for more sustainable energy sources, stricter requirements have been placed on electrode materials for sodium and potassium-ion batteries, which are expected to provide higher energy and power density while being affordable and sustainable. Vanadium sulfide-based materials have emerged as intriguing contenders for the next generation of anode materials due to their high theoretical capacity, abundant reserves, and cost-effectiveness. Despite these advantages, challenges such as limited cycle life and restricted ion diffusion coefficients continue to impede their effective application in sodium and potassium-ion batteries. To overcome the limitations associated with electrochemical performance and circumvent bottlenecks imposed by the inherent properties of materials at the bulk scale, this review comprehensively summarizes and analyzes the crystal structures, modification strategies, and energy storage processes of vanadium sulfide-based electrode materials for sodium and potassium-ion batteries. The objective is to guide the development of high-performance vanadium-based sulfide electrode materials with refined morphologies and/or structures, employing environmentally friendly and cost-efficient methods. Finally, future perspectives and research suggestions for vanadium sulfide-based materials are presented to propel practical applications forward.
https://doi.org/10.1002/admt.202301840