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Großmann, Max; Bohm, Sebastian; Heyder, Stefan; Schwarzburg, Klaus; Kleinschmidt, Peter; Runge, Erich; Hannappel, Thomas
Generalized modeling of photoluminescence transients. - In: Physica status solidi, ISSN 1521-3951, Bd. 260 (2023), 1, 2200339, S. 1-12

Time-resolved photoluminescence (TRPL) measurements and the extraction of meaningful parameters involve four key ingredients: a suitable sample such as a semiconductor double heterostructure, a state-of-the-art measurement setup, a kinetic model appropriate for the description of the sample behavior, and a general analysis method to extract the model parameters of interest from the measured TRPL transients. Until now, the last ingredient is limited to single curve fits, which are mostly based on simple models and least-squares fits. These are often insufficient for the parameter extraction in real-world applications. The goal of this article is to give the community a universal method for the analysis of TRPL measurements, which accounts for the Poisson distribution of photon counting events. The method can be used to fit multiple TRPL transients simultaneously using general kinematic models, but should also be used for single transient fits. To demonstrate this approach, multiple TRPL transients of a GaAs/AlGaAs heterostructure are fitted simultaneously using coupled rate equations. It is shown that the simultaneous fits of several TRPL traces supplemented by systematic error estimations allow for a more meaningful and more robust parameter determination. The statistical methods also quantify the quality of the description by the underlying physical model.



https://doi.org/10.1002/pssb.202200339
Wang, Zidong; Hong, Ping; Zhao, Huaping; Lei, Yong
Recent developments and future prospects of transition metal compounds as electrode materials for potassium-ion hybrid capacitors. - In: Advanced Materials Technologies, ISSN 2365-709X, Bd. 8 (2023), 3, 2200515, insges. 18 S.

Potassium-ion hybrid capacitors (PIHCs) have attracted considerable attention as emerging electrochemical energy storage devices for simultaneously achieving high energy and power density, which the key to success is the development of compatible electrode materials for both battery-type anode and capacitive cathode. Among numerous electrode materials, transition metal compounds (including oxides, chalcogenide, carbides, and nitrides) show great potential owing to their high theoretical capacity to achieve high energy density, but their sluggish reaction kinetics restrict the attainable power density. Hence, in the last few years, different strategies are proposed to improve the performance of transition metal compounds as electrode materials for PIHCs, and significant progress is achieved. Herein, this review outlines recent advances of employing transition metal compounds as electrode materials for PIHCs. The performance and challenges of different transition metal compounds are discussed in detail. Finally, the future prospects of practical applications of transition metal compounds in PIHCs are briefly discussed.



https://doi.org/10.1002/admt.202200515
Hülser, Tobias; Köster, Felix; Lüdge, Kathy; Jaurigue, Lina
Deriving task specific performance from the information processing capacity of a reservoir computer. - In: Nanophotonics, ISSN 2192-8614, Bd. 12 (2023), 5, S. 937-947

In the reservoir computing literature, the information processing capacity is frequently used to characterize the computing capabilities of a reservoir. However, it remains unclear how the information processing capacity connects to the performance on specific tasks. We demonstrate on a set of standard benchmark tasks that the total information processing capacity correlates poorly with task specific performance. Further, we derive an expression for the normalized mean square error of a task as a weighted function of the individual information processing capacities. Mathematically, the derivation requires the task to have the same input distribution as used to calculate the information processing capacities. We test our method on a range of tasks that violate this requirement and find good qualitative agreement between the predicted and the actual errors as long as the task input sequences do not have long autocorrelation times. Our method offers deeper insight into the principles governing reservoir computing performance. It also increases the utility of the evaluation of information processing capacities, which are typically defined on i.i.d. input, even if specific tasks deliver inputs stemming from different distributions. Moreover, it offers the possibility of reducing the experimental cost of optimizing physical reservoirs, such as those implemented in photonic systems.



https://doi.org/10.1515/nanoph-2022-0415
Link, Steffen; Dimitrova, Anna; Krischok, Stefan; Ivanov, Svetlozar
Electrochemical deposition of silicon in organic electrolytes. - In: Reference module in chemistry, molecular sciences and chemical engineering, (2023)

Electrodeposition is a versatile instrumental technique, already applied in many industrial fields. However, the deposition of silicon and other reactive elements is still challenging and requires further research and improvement. Accomplishing an efficient electrodeposition of silicon at room temperature is very attractive due to the high number of manufacturing technologies that would benefit from this approach. This work provides an overview of the electrochemical approaches for silicon deposition performed in organic electrolytes. The main factors that impact this process are individually discussed and exemplified with appropriately updated literature sources. Furthermore, the previously available research on characterization of electrodeposited silicon containing layers is provided. These studies are presented in the context of better understanding the structure, composition, and functional properties of the deposited silicon material, which may attract the attention of young academic scientists and process engineers.



https://doi.org/10.1016/B978-0-323-85669-0.00005-2
Wüster, Julian; Reetz, Andreas; Schmidt-Grund, Rüdiger; Knauer, Andrea; Sinzinger, Stefan
Approaches for the RCWA-based non-destructive characterization of subwavelength-structured gratings. - In: EOS Annual Meeting (EOSAM 2022), (2022), 05012, S. 1-2

Nano-structuring enables us to add additional degrees of freedom to the design of optical elements. Especially the possibility of controlling the polarization is of great interest in the field of nano-structured optics. For being able to exploit the whole range of form-birefringent phase shifts, the aspect ratios of the resulting element are typically much higher than the aspect ratios of conventional diffractive optical elements (DOEs), which does not only pose a challenge on fabrication but also on characterization. We evaluate several well-established approaches for the nondestructive characterization, including Müller-Matrix-Ellipsometry, measurement of the diffraction efficiencies, scattering measurements and calibration with rigorous coupled-wave modelling. The goal is to understand the challenges with all these techniques and combine them to a reliable method for structural reconnaisance of high aspect ratio nanostructures.



https://doi.org/10.1051/epjconf/202226605012
Cao, Yu; Wu, Yanjie; Tang, Xin; Zhou, Qi; Stapf, Siegfried; Mattea, Carlos; Li, Wei
Long-term efficiency for reducing entanglements of nascent polyethylene by a polystyrene-modified Ziegler-Natta catalyst. - In: Journal of applied polymer science, ISSN 1097-4628, Bd. 139 (2022), 11, 51790, S. 1-10

The weakly entangled ultrahigh molecular weight polyethylene (UHMWPE) was synthesized by a Ziegler-Natta catalyst, where the titanium tetrachloride was anchored on the polystyrene (PS)-modified silica. The PS chains were successfully incorporated into silica hierarchical pores even with the size less than 10 nm through the in situ free-radical polymerization of styrene. The self-diffusion coefficient and crystallization of probing molecules inside the pores were investigated by the pulsed field gradient NMR and thermoporosimetry to address the swollen behavior of incorporated PS blocks. This PS blocks compartmentalized the polyethylene chains, where the less entangled UHMWPE was synthesized with an exceptional activity at 70˚C. The ubiquitous PS isolators effectively hindered the formation of chains overlaps during the polymerization, showing a long-term efficiency to reduce the entanglements of nascent UHMWPE even at 4 h of polymerization The toughness/stiffness/strength balance of weakly entangled UHMWPE was significantly improved.



https://doi.org/10.1002/app.51790
Calderón, Jesús A.; Tafur, Julio; Barriga, Benjamín; Alencastre, Jorge; Solano, Gonzalo; Urbizagástegui, Rodrigo; Lozano, John; Chancán, Marvin
Optimal plant growth through thermo mechatronic analysis. - In: , (2022), S. 65-70

This work is described as a proposal to apply modern control techniques and automation tools for optimal plant growth, also it was based on key agricultural strategies that were developed by ancient civilizations such as the Inca Empire. Many of them ancient techniques including the Inca engineering of andenes were forgotten or set aside through time. In this research, however, some of these key techniques are revisited to analyze and evaluate optimal plant growth using sensors and actuators that were not available in ancient civilizations. In addition, predictive and adaptive mathematical models are used for plant growth analysis of thermodynamic parameters such as temperature, humidity and potential of Hydrogen (pH). Furthermore, there were compared performances of sensors (electromechanical sensors) with designed sensors that were based in nanostructures, because of better study of the plant growth techniques.



Calderón, Jesús A.; Barriga G., E. Benjamín; Tafur, Julio C.; Ccarita, Alan; Lozano, John; Urbizagástegui, Rodrigo
Intelligent sensors based on amorphous nanostructures according to achieve an optimal waste collection in Lima Peru. - In: ICIEA 2022, (2022), S. 1606-1611

An optimal waste collection is a very complicated task in different countries. However, this task is more intricate, when there is not an organized procedure between people, government and technology. In this research it was studied and proposed strategies, to optimize the waste collection by technical suggestions, that were based on mathematical analysis and new technologies applications of sensors based on nanostructures due to this kind of sensors have good performance to measure physical variables in not simple places and conditions, such as around waste. Hence the reason, this work is prepared to contribute in the development of sensors based on nanostructures according to detect the physical variables: temperature, humidity, infrared reflection, moreover carbon dioxide (CO2) and methane (CH4) gases, which help to monitor the consequences of a not correct waste collection.As dependence on central and local government rules of waste management, it could be possible to find solution about organized waste collection, in which every family and walkers in streets would have the task to select the organic and inorganic garbage before the government trucks take the contents of the garbage trash cans to the landfill garbage dumps. However, many times the trash cans are not taken on time by the government trucks and garbage from them are producing gases and decomposition that causes contamination that damages health. Therefore, in this work there are proposed designed intelligent sensors, which are fixed in the trash cans due to measure physical parameters to give alarm for administrators controllers of boxes and to enhance the garbage selections from homes and streets to the main garbage landfills of the city. In other side, there will not be right solution in the waste collection, no matter the high advantage technologies, while humans could not be sensitive under this problematic. There are cleaned areas in cities, as for example touristic places, nevertheless, there are plenty places, where are not cared and people in streets through residual solids around, hence the technical solution will be useful only whether humans can get the environment caring condition compromise.



https://doi.org/10.1109/ICIEA54703.2022.10006092
Bohm, Sebastian; Runge, Erich
Multiphysics simulation of fluid interface shapes in microfluidic systems driven by electrowetting on dielectrics. - In: Journal of applied physics, ISSN 1089-7550, Bd. 132 (2022), 22, S. 224702-1-224702-17

We present a highly efficient simulation method for the calculation of three-dimensional quasi-static interface shapes under the influence of electric fields. The method is especially useful for the simulation of microfluidic systems driven by electrowetting on dielectrics because it accounts automatically and inherently for the highly non-trivial interface shape in the vicinity of the triple-phase contact. In particular, the voltage independence of the local contact angle predicted based on analytical considerations is correctly reproduced in all our simulations. For the calculation of the shape of the interface, the geometry is triangulated and the mesh nodes are shifted until the system energy becomes minimal. The same mesh is also used to calculate the electric field using the boundary-element method. Therefore, only the surface of the geometry needs to be meshed, and no volume meshes are involved. The method can be used for the simulation of closed systems with a constant volume (e.g., droplet-based microfluidics) while preserving the volume very precisely as well as open systems (e.g., the liquid-air interface within micro-cavities or capillaries). Additional effects, such as the influence of gravitational forces, can easily be taken into account. In contrast to other efficient simulations, such as the volume-of-fluid, level-set, or phase-field methods, ideally, sharp interfaces are obtained. We calculate interface shapes for exemplary systems and compare with analytical as well as experimental results.



https://doi.org/10.1063/5.0110149
Brekotkin, I. V.; Fatkullin, Nail F.; Lindt, Kevin; Mattea, Carlos; Stapf, Siegfried
On the theory of the spin I = 1/2 double quantum NMR: effects of spins spatial displacements between RF pulses. - In: The journal of chemical physics, ISSN 1089-7690, Bd. 157 (2022), 22, S. 224108-1-224108-7

Spatial displacements of spins between radio frequency pulses in a Double-Quantum (DQ) nuclear magnetic resonance pulse sequence generate additional terms in the effective DQ Hamiltonian. We derive a simple expression that allows the estimation and control of these contributions to the initial rise of the DQ build up function by variation of experimental parameters in systems performing anomalous diffusion. The application of polymers is discussed.



https://doi.org/10.1063/5.0124510