Geförderte OA-Publikationen

Friction stir welding (FSW) is a solid-state joining process with a wide range of applications in the E-mobility, automotive, aerospace and energy industries. However, FSW is subjected to specific challenges including comparatively high process forces and high requirements on the clamping technique as well as tool wear resulting from the tool-workpiece interaction and thermo-mechanical stresses. Geometric-related tool wear can cause premature tool failure, process instabilities or weld seam irregularities. Therefore, tool wear in general, wear limits and tool life are essential factors for the efficient and sustainable implementation of friction stir welding. Against this background, this study analysed areas of significant tool wear on the shoulder and probe as a function of process temperature, weld seam length and weld seam quality. This provided functional correlations for determining limiting conditions on maximum tolerable tool wear. Geometrical deviations of the tool, induced by wear, were detected experimentally at different measuring points on the probe and shoulder and varying weld seam length. The investigations were carried out using a force-controlled robotized welding setup in which AA-6060-T66 sheets with a thickness of 5 mm were joined by weld seams up to 500 m in length. To identify the maximum tolerable tool wear, the weld seam properties were determined by visual and metallographic inspections and by tensile tests at 50-m intervals on the weld seam. It was shown that a 50% reduction in rotational speed (lower temperatures) resulted in less wear and thus in an increase of tool life of up to 150%. In addition, it was shown that the shoulder, like the probe, was also subject to significant wear. These results can be incorporated into FSW maintenance schedules to maximize tool life and minimize scrap rates.

Time-resolved photoluminescence (TRPL) measurements and the extraction of meaningful parameters involve four key ingredients: a suitable sample such as a semiconductor double heterostructure, a state-of-the-art measurement setup, a kinetic model appropriate for the description of the sample behavior, and a general analysis method to extract the model parameters of interest from the measured TRPL transients. Until now, the last ingredient is limited to single curve fits, which are mostly based on simple models and least-squares fits. These are often insufficient for the parameter extraction in real-world applications. The goal of this article is to give the community a universal method for the analysis of TRPL measurements, which accounts for the Poisson distribution of photon counting events. The method can be used to fit multiple TRPL transients simultaneously using general kinematic models, but should also be used for single transient fits. To demonstrate this approach, multiple TRPL transients of a GaAs/AlGaAs heterostructure are fitted simultaneously using coupled rate equations. It is shown that the simultaneous fits of several TRPL traces supplemented by systematic error estimations allow for a more meaningful and more robust parameter determination. The statistical methods also quantify the quality of the description by the underlying physical model.

This paper considers the structure consisting of the set of all words over a given alphabet together with the subword relation, regular predicates, and constants for every word. We are interested in the counting extension of first-order logic by threshold counting quantifiers. The main result shows that the two-variable fragment of this logic can be decided in twofold exponential alternating time with linearly many alternations (and therefore in particular in twofold exponential space as announced in the conference version (Kuske and Schwarz, in: MFCS’20, Leibniz International Proceedings in Informatics (LIPIcs) vol. 170, pp 56:1-56:13. Schloss Dagstuhl - Leibniz-Zentrum für Informatik, 2020) of this paper) provided the regular predicates are restricted to piecewise testable ones. This result improves prior insights by Karandikar and Schnoebelen by extending the logic and saving one exponent in the space bound. Its proof consists of two main parts: First, we provide a quantifier elimination procedure that results in a formula with constants of bounded length (this generalises the procedure by Karandikar and Schnoebelen for first-order logic). From this, it follows that quantification in formulas can be restricted to words of bounded length, i.e., the second part of the proof is an adaptation of the method by Ferrante and Rackoff to counting logic and deviates significantly from the path of reasoning by Karandikar and Schnoebelen.

Muscle fatigue as a defense body mechanism against overload is a result of the products of incomplete oxygen oxidation such as reactive oxygen species. Hence, C60 fullerene as a powerful nanoantioxidant can be used to speed up the muscle recovery process after fatigue. Here, the residual effect of C60 fullerene on the biomechanical and biochemical markers of the development of muscle soleus fatigue in rats for 2 days after 5 days of its application was studied. The known antioxidant N-acetylcysteine (NAC) was used as a comparison drug. The atomic force microscopy to determine the size distribution of C60 fullerenes in an aqueous solution, the tensiometry of skeletal muscles, and the biochemical analysis of their tissues and rat blood were used in this study. It was found that after the cessation of NAC injections, the value of the integrated muscle power is already slightly different from the control (5%-7%) on the first day, and on the second day, it does not significantly differ from the control. At the same time, after the cessation of C60 fullerene injections, its residual effect was 45%-50% on the first day, and 17%-23% of the control on the second one. A significant difference (more than 25%) between the pro- and antioxidant balance in the studied muscles and blood of rats after the application of C60 fullerene and NAС plays a key role in the long-term residual effect of C60 fullerene. This indicates prolonged kinetics of C60 fullerenes elimination from the body, which contributes to their long-term (at least 2 days) compensatory activation of the endogenous antioxidant system in response to muscle stimulation, which should be considered when developing new therapeutic agents based on these nanoparticles.