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Rothe, Karl; Néel, Nicolas; Kröger, Jörg
Unveiling the nature of atomic defects in graphene on a metal surface. - In: Beilstein journal of nanotechnology, ISSN 2190-4286, Bd. 15 (2024), S. 416-425

Low-energy argon ion bombardment of graphene on Ir(111) induces atomic-scale defects at the surface. Using a scanning tunneling microscope, the two smallest defects appear as a depression without discernible interior structure suggesting the presence of vacancy sites in the graphene lattice. With an atomic force microscope, however, only one kind can be identified as a vacancy defect with four missing carbon atoms, while the other kind reveals an intact graphene sheet. Spatially resolved spectroscopy of the differential conductance and the measurement of total-force variations as a function of the lateral and vertical probe–defect distance corroborate the different character of the defects. The tendency of the vacancy defect to form a chemical bond with the microscope probe is reflected by the strongest attraction at the vacancy center as well as by hysteresis effects in force traces recorded for tip approach to and retraction from the Pauli repulsion range of vertical distances.



https://doi.org/10.3762/bjnano.15.37
Fröhlich, Thomas; Kissinger, Thomas; Manske, Eberhard
Process measurement technology and precision measurement technology :
Prozessmesstechnik und Präzisionsmesstechnik. - In: Technisches Messen, ISSN 2196-7113, Bd. 91 (2024), 5, S. 231-232
Editorial

https://doi.org/10.1515/teme-2024-0041
Tschumak, Alexej; Feldhoff, Frank; Klefenz, Frank
The switching and learning behavior of an octopus cell implemented on FPGA. - In: Mathematical biosciences and engineering, ISSN 1551-0018, Bd. 21 (2024), 4, S. 5762-5781

A dendrocentric backpropagation spike timing-dependent plasticity learning rule has been derived based on temporal logic for a single octopus neuron. It receives parallel spike trains and collectively adjusts its synaptic weights in the range [0, 1] during training. After the training phase, it spikes in reaction to event signaling input patterns in sensory streams. The learning and switching behavior of the octopus cell has been implemented in field-programmable gate array (FPGA) hardware. The application in an FPGA is described and the proof of concept for its application in hardware that was obtained by feeding it with spike cochleagrams is given; also, it is verified by performing a comparison with the pre-computed standard software simulation results.



https://doi.org/10.3934/mbe.2024254
Bohm, Sebastian; Phi, Hai Binh; Dittrich, Lars; Runge, Erich
Chip-integrated non-mechanical microfluidic pump driven by electrowetting on dielectrics. - In: Lab on a chip, ISSN 1473-0189, Bd. 0 (2024), 0, insges. 13 S.

A microfluidic pump is presented that generates its pumping action via the EWOD (electrowetting-on-dielectric) effect. The flow is generated by the periodic movement of liquid-vapor interfaces in a large number (≈10^6) of microcavities resulting in a volume change of approx. 0.5 pl per cavity per pump stroke. The total flow resulting from all microcavities adds up to a few hundred nanolitres per cycle. Passive, topologically optimized, non-mechanical Tesla valves are used to rectify the flow. As a result, the micropump operates without any moving components. The dimensioning, fabrication, and characterization process of the micropump are described. Device fabrication is done using conventional manufacturing processes from microsystems technology, enabling cost-effective mass production on wafer-level without additional assembly steps like piezo chip-level bonding, etc. This allows for direct integration into wafer-based microfluidic or lab-on-a-chip applications. Furthermore, first measurement results obtained with prototypes of the micropump are presented. The voltage- and frequency-dependent pump performance is determined. The measurements show that a continuous flow rate larger than 0.2 ml min^−1 can be achieved at a maximum pump pressure larger than 12 mbar.



https://doi.org/10.1039/D4LC00178H
Sayahkarajy, Mostafa; Witte, Hartmut; Faudzi, Ahmad Athif Mohd
Chorda dorsalis system as a paragon for soft medical robots to design echocardiography probes with a new SOM-based steering control. - In: Biomimetics, ISSN 2313-7673, Bd. 9 (2024), 4, 199, S. 1-22

Continuum robots play the role of end effectors in various surgical robots and endoscopic devices. While soft continuum robots (SCRs) have proven advantages such as safety and compliance, more research and development are required to enhance their capability for specific medical scenarios. This research aims at designing a soft robot, considering the concepts of geometric and kinematic similarities. The chosen application is a semi-invasive medical application known as transesophageal echocardiography (TEE). The feasibility of fabrication of a soft endoscopic device derived from the Chorda dorsalis paragon was shown empirically by producing a three-segment pneumatic SCR. The main novelties include bioinspired design, modeling, and a navigation control strategy presented as a novel algorithm to maintain a kinematic similarity between the soft robot and the rigid counterpart. The kinematic model was derived based on the method of transformation matrices, and an algorithm based on a self-organizing map (SOM) network was developed and applied to realize kinematic similarity. The simulation results indicate that the control method forces the soft robot tip to follow the path of the rigid probe within the prescribed distance error (5 mm). The solution provides a soft robot that can surrogate and succeed the traditional rigid counterpart owing to size, workspace, and kinematics.



https://doi.org/10.3390/biomimetics9040199
Iliasov, Aleksandr I.; Matsukatova, Anna N.; Emelyanov, Andrey V.; Slepov, Pavel S.; Nikiruy, Kristina; Rylkov, Vladimir V.
Adapted MLP-Mixer network based on crossbar arrays of fast and multilevel switching (Co-Fe-B)x(LiNbO3)100-x nanocomposite memristors. - In: Nanoscale horizons, ISSN 2055-6764, Bd. 9 (2024), 2, S. 238-247

MLP-Mixer based on multilayer perceptrons (MLPs) is a novel architecture of a neuromorphic computing system (NCS) introduced for image classification tasks without convolutional layers. Its software realization demonstrates high classification accuracy, although the number of trainable weights is relatively low. One more promising way of improving the NCS performance, especially in terms of power consumption, is its hardware realization using memristors. Therefore, in this work, we proposed an NCS with an adapted MLP-Mixer architecture and memristive weights. For this purpose, we used a passive crossbar array of (Co-Fe-B)x(LiNbO3)100−x memristors. Firstly, we studied the characteristics of such memristors, including their minimal resistive switching time, which was extrapolated to be in the picosecond range. Secondly, we created a fully hardware NCS with memristive weights that are capable of classification of simple 4-bit vectors. The system was shown to be robust to noise introduction in the input patterns. Finally, we used experimental memristive characteristics to simulate an adapted MLP-Mixer architecture that demonstrated a classification accuracy of (94.7 ± 0.3)% on the Modified National Institute of Standards and Technology (MNIST) dataset. The obtained results are the first steps toward the realization of memristive NCS with a promising MLP-Mixer architecture.



https://doi.org/10.1039/D3NH00421J
Jiménez, Juan Jesús; Jaekel, Konrad; Pauly, Christoph; Schäfer, Christian; Bartsch, Heike; Mücklich, Frank; Morales Sánchez, Francisco Miguel
Impact of sample preparation approach on transmission electron microscopy investigation of sputtered AlNi multilayers used for reactive soldering. - In: Advanced engineering materials, ISSN 1527-2648, Bd. 0 (2024), 0, 2302215, S. 1-12

This work presents studies of sputtered Al/Ni reactive multilayers by transmission electron microscopy. They are prepared for these analyses by three methods (both Ga- and Xe-based focused ion beam, FIB, and tripod polishing plus Ar+ ion milling in precision ion polishing system, PIPS) to check their impact on these materials. Every sample shows polycrystalline and mostly chemically pure Al/Ni layers. They also hint existence of intermetallic compounds, especially the tripod-prepared sample. These intermetallics first originate from the sputtering process. The layers are increasingly rough along the growth direction. Other remarkable findings can be highlighted. First, the heating operations applied during the tripod polishing preparation lead to recrystallization and blurred Al/Ni interfaces due to increased metals reactions, although additional contributions by roughness and preparation thickness to the current compositional uncertainties must be distinguished by optimizing future sample fabrications and preparations. Second, Xe-based FIB leads to lamellae with seemingly low contamination, although Ga-FIB is a potentially good alternative. Finally, FIB is better to study cross-section preparations of pristine Al/Ni multilayers, whereas the present tripod polishing procedures are unsuitable for this purpose but allow to observe the beginning of Al/Ni transformations upon heating, which is interesting for the technological optimization of these materials.



https://doi.org/10.1002/adem.202302215
Phani Kumar, Bandaru V. N.; Lobo, Nitin P.; Mattea, Carlos; Stapf, Siegfried
Exploring crystal-phase molecular dynamics of the low-viscous mesogen 6CHBT: a combined FFC and high-field NMR relaxometry investigation. - In: The journal of physical chemistry, ISSN 1520-5207, Bd. 128 (2024), 16, S. 3997-4007

The molecular dynamics study of thermotropic mesogens exhibiting the crystal phases is valuable in unraveling the complex global (collective) and local (noncollective) motions executed by liquid crystal molecules, which would further advance the existing knowledge on orientationally disordered crystalline (ODIC) phases. Toward the fulfillment of such a task, a combined nuclear magnetic resonance (NMR) relaxometry approach employing the fast field cycling (FFC) NMR (10 kHz-30 MHz) and high-field pulsed NMR (400 MHz) techniques is utilized to sample the broad frequency range offered by molecular motions in the crystal phase of 4-(trans-4′-n-hexylcyclohexyl)-isothiocyanatobenzene (6CHBT). The validity of the observed relaxation data is tested and interpreted by the Bloembergen-Purcell-Pound (BPP) model involving the superposition of four mutually independent Lorentzian spectral densities, reflecting molecular dynamical processes on different time scales. The salient feature of the detailed analysis reveals that the lengthening of temporal dynamics in the crystal phase due to molecular rotations by jumps, which are of intermolecular origin, is evident and further supports the presence of collective-like local dynamics. The analysis does permit decoupling of the molecular reorientations about their short axes (∼100 ns) as well as long axes (∼50 ns) and methyl group rotations (∼0.5 ns) on distinct time scales. The activation energies for reorientations about the short axes and methyl group rotations are found to be 27.3 ± 2.7 and 15.8 ± 1.1 kJ/mol, respectively. The fast methyl rotations in the crystal phase of 6CHBT obtained from FFC NMR are further well complemented by high-field NMR, where 1H NMR line shapes are relatively narrow when compared to those of the nematic phase.



https://doi.org/10.1021/acs.jpcb.3c08259
Rashidifar, Ali; Römer, Florian; Semper, Sebastian; Gutzeit, Nam; Del Galdo, Giovanni
Broadband DRA with uniform angular dependent delay for indoor localization. - In: IEEE access, ISSN 2169-3536, Bd. 12 (2024), S. 63644-63654

Estimating the Time Difference of Arrival (TDoA), is a simple yet reliable technique to accurately perform an indoor monostatic localization. To implement TDoA estimation, one approach is to utilize a broadband radar system equipped with multiple receiving antenna elements. To obtain the Time of Arrival (ToA) at each antenna element, the round-trip time is required. However, the round-trip time does not only consist of the propagation delay in free space but the propagation delay within the antenna as well. To perform the localization precisely, it is desired that an antenna element introduces a uniform delay in all directions. To this end, a compact rectangular dielectric resonator antenna is designed for the operating frequency of 6.5 GHz with a fractional bandwidth of 20%. Al2O3 with a dielectric constant of 9.8 is used for the substrate as well as the dielectric resonator. The antenna is designed to provide a high correlation between the input and the output pulses. To investigate the correlation, the antenna is excited with a modulated Gaussian pulse and the radiated pulses are studied. The antenna possesses an excellent behavior in terms of pulse preservation for the upper hemisphere. Therefore, when incoming pulses from the same distance but different directions impinge on the antenna, they reach the port of the antenna at a similar time. It is shown that this feature of the proposed antenna allows the utilization of TDoA estimation without the need for a calibration step. The characteristics of the antenna are verified by simulation and measurement.



https://doi.org/10.1109/ACCESS.2024.3395124
Meier, Martin; Weichert, Christoph; Kawohl, Jan; Flügge, Jens; Manske, Eberhard
Vergleich von vollständig fasergekoppelten Interferometersystemen unter Vakuumbedingungen :
Comparison of full fiber coupled interferometer systems under vacuum conditions. - In: Technisches Messen, ISSN 2196-7113, Bd. 91 (2024), 5, S. 281-289

The PTB built a comparator setup for testing length measuring systems under vacuum conditions. The setup is equipped with a linear stage which is operated in a closed loop using the feedback of a 1.5D encoder system with three encoder heads for length and vertical rotation angle and exhibits a movement range of 150 mm. The main measurement system is a heterodyne interferometer with periodic nonlinearities with amplitudes below 10 pm. The comparator setup was characterized using a mirror mounted on the stage reflecting the measurement as well as the reference beams. By these means, the resolution, the stability of the setup as well as the influence of guiding errors on position-dependent measurement deviations of the fully fiber coupled interferometer were investigated. A position-depending error was observed which was resulting from the variation of the performance of the coupling into the multi-mode fibers used to transfer the superposed beams to the photoreceivers. The measured deviations were 1.5 nm or 0.2 nm over 70 mm travel range depending on the core diameter of the multi-mode fibers of 50 µm and 200 µm, respectively. Three different commercial fiber interferometer systems were analysed under vacuum conditions with the comparator setup. All tested systems are working with light sources with a wavelength of approximately 1535 nm but differ in the amplitude of their periodic nonlinearities in the range between 10 pm and 29 nm. The tests of their resolution and stability were limited by vibrations in the comparator setup and the lack of adequate synchronization capabilities of the data acquisition of these systems.



https://doi.org/10.1515/teme-2024-0011