Zeitschriftenaufsätze

Quantum computers represent a prominent example of technology harnessing quantum phenomena for practical applications. Implementations based on superconducting solid-state qubits play a leading role. These have facilitated the implementation of the first commercially viable quantum computers through the use of well-established and scalable fabrication technologies. As the number of qubits in these systems is continuously increasing, there is an urgent need to advance wiring and integration methods. Specifically, the demand for high-frequency control and readout lines within the millikelvin coolers introduces unwanted heat load. As a scalable alternative, superconducting digital electronics has been proposed as a promising candidate for direct interfacing with superconducting quantum circuits. We, therefore, advanced our well-established cross-type, sub-micrometer-sized Nb-based Josephson junction technology for analog circuits to allow for the implementation of digital circuits. Thus, an advanced mixed signal process CJ2 hosts both, analog and digital circuits, on a single chip, using Josephson junctions of a wide critical current range. We discuss the technology and the realization of first circuits as well as results of basic logic gate and dc-SQUID operations. This advanced technology CJ2 enables the development of digital interfaces for quantum circuits by academic and industrial partners in the framework of the European FLUXONICS foundry.

Renewable (“green”) hydrogen production through direct photoelectrochemical (PEC) water splitting is a potential key contributor to the sustainable energy mix of the future. We investigate the potential of indium phosphide (InP) as a reference material among III-V semiconductors for PEC and photovoltaic (PV) applications. The p(2 × 2)/c(4 × 2)-reconstructed phosphorus-terminated p-doped InP(100) (P-rich p-InP) surface is the focus of our investigation. We employ time-resolved two-photon photoemission (tr-2PPE) spectroscopy to study electronic states near the band gap with an emphasis on normally unoccupied conduction band states that are inaccessible through conventional single-photon emission methods. The study shows the complexity of the p-InP electronic band structure and reveals the presence of at least nine distinct states between the valence band edge and vacuum energy, including a valence band state, a surface defect state pinning the Fermi level, six unoccupied surface resonances within the conduction band, as well as a cluster of states about 1.6 eV above the CBM, identified as a bulk-to-surface transition. Furthermore, we determined the decay constants of five of the conduction band states, enabling us to track electron relaxation through the bulk and surface conduction bands. This comprehensive understanding of the electron dynamics in p-InP(100) lays the foundation for further exploration and surface engineering to enhance the properties and applications of p-InP-based III-V-compounds for, e.g., efficient and cost-effective PEC hydrogen production and highly efficient PV cells.

Fiber-reinforced polymer (FRP) composites are particularly suitable for spring applications due to numerous advantages like lightweight design, intrinsic damping, or chemical resistance. Although there are many studies on the properties of FRPs and even some on springs made out of these materials, there is no holistic method for FRP spring design. Therefore, this article focuses on a new approach that combines all relevant design steps. This includes a spring-related overview of requirements and associated FRP properties, as well as recommendations regarding material and spring type selection with a specialization on polymer composite volute springs. Thereupon, a mountain bike rear suspension spring was designed and produced. These carbon fiber-reinforced polymer (CFRP) lightweight spring, which weighs only half of the metal spring, was examined in static and cyclic experiments. Important results of the tests are a lower spring rate than theoretically expected as well as a loss of stiffness of the spring of about 25% after 25,000 full deflections just before failure. Downhill riding tests were carried out and showed comparable driving characteristics as when using conventional steel springs. The research is a contribution to FRP spring design considerations as well as to extend the range of applications for composite springs, and especially volute springs, in the future.

Due to their high specific capacity and long cycle life, bimetallic sulfides are the preferred choice of researchers as anodes in sodium-ion batteries (SIBs). However, studies indicate that this class of materials often requires expensive elements such as Co, Sb, Sn, etc., and their performance is insufficient with the use of inexpensive Fe, V alone. Therefore, there is a need to explore the relationship between metal cations and anode performance so that the requirements of cost reduction and performance enhancement can be met simultaneously. In this work, a series of partially replaced sulfides with different cation ratios have been prepared by a hydrothermal method followed by heat treatment. By partially replacing Co in NiCo sulfides, all samples show improved capacity and stability over the original NiCo sulfides. As a result, the metal elements have different oxidation states, which leads to a higher capacity through their synergistic effects on each other. Mn-NiCoS with 10% replacement showed satisfactory capacity (721.09 mAh g^−1 at 300 mA g^−1, 662.58 mAh g^−1 after 20 cycles) and excellent cycle life (85.41% capacity retention after 1000 cycles at 2000 mA g^−1).

Spectral analysis of repeatedly evoked potentials (EPs) is challenging since recordings contain a superposition of evoked signals and spontaneous activity. We developed a novel approach, N-interval Fourier Transform Analysis (N-FTA), which allows for reliable separation and simultaneous assessment of triggered and background spectral components. Median nerve stimulation data from a total of eleven volunteers recorded in two labs with different experimental settings were investigated. Consistently, short latency spectral components were mainly contained in the gamma and high gamma bands. In contrast, spontaneous activity displayed a 1/f spectral profile with distinct alpha and beta peaks. Spontaneous power spectral densities (PSDs) obtained for real and sham stimulation were highly comparable. The low frequency background PSD was more than two orders of magnitude above the spectral short latency peaks. Within the 30Hz to 90Hz band, the evoked peaks were -17dB to -4dB below the background suggesting that target band filtered short latency deflection might be extracted using less than 100 trials. SEPs following tibial nerve stimulation (3 subjects) displayed a narrower spectral band at about half the bandwidth as compared to median nerve stimulation. Evoked peaks were between 30Hz and 37Hz at PSD levels being -10dB to -4dB below the background activity. These spectral peaks were related to the short latency response of typical W-morphology. Cortical short latency responses are contained in distinct spectral target bands which are much narrower than the standard bandwidth recommendations for routine recordings. In particular, the high pass corner frequency may be selected about one order of magnitude above the current standard. This might render SEP recordings more robust since it eases the suppression of spontaneous activity and movement artifacts such as eye-blinks. Real-time zero-phase filters are required for translating these findings into improved recording systems.