Publikationsliste FG Nanotechnologie

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Erstellt: Wed, 17 Aug 2022 23:02:09 +0200 in 0.5672 sec

Grieseler, Rolf; Gallino, Isabella; Duboiskaya, Natallia; Döll, Joachim; Shekhawat, Deepshikha; Reiprich, Johannes; Guerra, Jorge A.; Hopfeld, Marcus; Honig, Hauke; Schaaf, Peter; Pezoldt, Jörg;
Silicon carbide formation in reactive silicon-carbon multilayers. - In: Materials science forum, ISSN 1662-9752, Bd. 1062 (2022), S. 44-48

An alternative low thermal budget silicon carbide syntheses route is presented. The method is based on self-propagating high-temperature synthesis of binary silicon-carbon-based reactive mul­tilayers. With this technique, it is possible to obtain cubic polycrystalline silicon carbide at relatively low annealing temperatures by a solid state reaction. The reaction starts above 600 ˚C. The transformation process proceeds in a four-step process. The reaction enthalpy was determined to be (-70 ± 4) kJ/mol.
Mathew, Sobin; Lebedev, Sergey P.; Lebedev, A. A.; Hähnlein, Bernd; Stauffenberg, Jaqueline; Manske, Eberhard; Pezoldt, Jörg;
Silicon carbide - graphene nano-gratings on 4H and 6H semi-insulating SiC. - In: Materials science forum, ISSN 1662-9752, Bd. 1062 (2022), S. 170-174

A technical methodology of fabrication of hierarchically scaled multitude graphene nanogratings with varying pitches ranging from the micrometer down to sub 40 nm scale combined with sub 10 nm step heights on 4H and 6H semi-insulating SiC for length scale measurements is proposed. The nanogratings were fabricated using electron-beam lithography combined with dry etching of graphene, incorporating a standard semiconductor processing technology. A scientific evaluation of critical dimension, etching step heights, and surface characterization of graphene nanograting on both polytypes were compared and evaluated.
Kurtash, Vladislav; Thiele, Sebastian; Mathew, Sobin; Jacobs, Heiko O.; Pezoldt, Jörg;
Designing MoS2 channel properties for analog memory in neuromorphic applications. - In: Journal of vacuum science & technology, ISSN 2166-2754, Bd. 40 (2022), 3, S. 030602-1-030602-5

In this paper, we introduce analog nonvolatile random access memory cells for neuromorphic computing. The analog memory cell MoS2 channel is designed based on the simulation model including Fowler-Nordheim tunneling through a charge-trapping stack, trapping process, and transfer characteristics to describe a full write/read circle. 2D channel materials provide scaling to higher densities as well as preeminent modulation of the conductance by the accumulated space charge from the oxide trapping layer. In this paper, the main parameters affecting the distribution of memory states and their total number are considered. The dependence of memory state distribution on channel doping concentration and the number of layers is given. In addition, how the nonlinearity of memory state distribution can be overcome by variation of operating conditions and by applying pulse width modulation to the bottom gate voltage is also shown.
Shekhawat, Deepshikha; Vauth, Maximilian; Pezoldt, Jörg;
Size dependent properties of reactive materials. - In: Inorganics, ISSN 2304-6740, Bd. 10 (2022), 4, 56, S. 1-19

The nature of the self-sustained reaction of reactive materials is dependent on the physical, thermal, and mechanical properties of the reacting materials. These properties behave differently at the nano scale. Low-dimensional nanomaterials have various unusual size dependent transport properties. In this review, we summarize the theoretical and experimental reports on the size effect on melting temperature, heat capacity, reaction enthalpy, and surface energy of the materials at nano scale because nanomaterials possess a significant change in large specific surface area and surface effect than the bulk materials. According to the theoretical analysis of size dependent thermodynamic properties, such as melting temperature, cohesive energy, thermal conductivity and specific heat capacity of metallic nanoparticles and ultra-thin layers varies linearly with the reciprocal of the critical dimension. The result of this scaling relation on the material properties can affect the self-sustained reaction behavior in reactive materials. Resultant, powder compacts show lower reaction propagation velocities than bilayer system, if the particle size of the reactants and the void density is decreased an increase of the reaction propagation velocity due to an enhanced heat transfer in reactive materials can be achieved. Standard theories describing the properties of reactive material systems do not include size effects.
Isaac, Nishchay Angel; Pikaar, Ilje; Biskos, George;
Metal oxide semiconducting nanomaterials for air quality gas sensors: operating principles, performance, and synthesis techniques. - In: Microchimica acta, ISSN 1436-5073, Bd. 189 (2022), 5, 196, S. 1-22

To meet requirements in air quality monitoring, sensors are required that can measure the concentration of gaseous pollutants at concentrations down to the ppb and ppt levels, while at the same time they exhibiting high sensitivity, selectivity, and short response/recovery times. Among the different sensor types, those employing metal oxide semiconductors (MOSs) offer great promises as they can be manufactured in easy/inexpensive ways, and designed to measure the concentration of  a wide range of target gases. MOS sensors rely on the adsorption of target gas molecules on the surface of the sensing material and the consequent capturing of electrons from the conduction band that in turn affects their conductivity. Despite their simplicity and ease of manufacturing, MOS gas sensors are restricted by high limits of detection (LOD; which are typically in the ppm range) as well as poor sensitivity and selectivity. LOD and sensitivity can in principle be addressed by nanostructuring the MOSs, thereby increasing their porosity and surface-to-volume ratio, whereas selectivity can be tailored through their chemical composition. In this paper we provide a critical review of the available techniques for nanostructuring MOSs using chemiresistive materials, and discuss how these can be used to attribute desired properties to the end gas sensors. We start by describing the operating principles of chemiresistive sensors, and key material properties that define their performance. The main part of the paper focuses on the available methods for synthesizing nanostructured MOSs for use in gas sensors. We close by addressing the current needs and provide perspectives for improving sensor performance in ways that can fulfill requirements for air quality monitoring.
Thiele, Sebastian; Eliseyev, Ilya A.; Smirnov, Alexander N.; Jacobs, Heiko O.; Davydov, Valery Y.; Schwierz, Frank; Pezoldt, Jörg;
Electric bias-induced edge degradation of few-layer MoS2 devices. - In: Materials today, ISSN 2214-7853, Bd. 53 (2022), 2, S. 281-284

In this work, we experimentally investigate the effects of electric bias on the degradation of few-layer MoS2 back-gated field-effect transistors in ambient air. The devices were fabricated using mechanically exfoliated MoS2 flakes, which were transferred to a Si/SiO2 substrate by a PDMS-based transfer. We report an accelerated electric bias-induced degradation of the devices under investigation and used optical and scanning electron microscopy (SEM) to monitor changes of the morphology of the MoS2 channel. In particular, we found a linear dependency of the degradation on the electric field between the Ti/Au source and drain contacts. In addition, we identify four regions in which morphological changes occur, of which the edges of the MoS2 channel are most affected.
Mathew, Sobin; Lebedev, Sergey P.; Lebedev, Alexander A.; Hähnlein, Bernd; Stauffenberg, Jaqueline; Udas, Kashyap; Jacobs, Heiko O.; Manske, Eberhard; Pezoldt, Jörg;
Nanoscale surface morphology modulation of graphene - i-SiC heterostructures. - In: Materials today, ISSN 2214-7853, Bd. 53 (2022), 2, S. 289-292

A multitude gratings design consists of gratings with different pitches ranging from the micrometre down to sub 40 nm scale combined with sub 10 nm step heights modulating the surface morphology for length scale measurements is proposed. The surface morphology modulation was performed using electron beam lithography incorporating a standard semiconductor processing technology. The critical dimension, edge roughness, step heights and line morphology in dependence on the grating pitch is studied.
Reiprich, Johannes;
Localized and programmable material transport and deposition by corona discharge. - Ilmenau : Universitätsbibliothek, 2022. - 1 Online-Ressource (xiii, 133, XXIX Seiten)
Technische Universität Ilmenau, Dissertation 2022

Der Transport von Materialien und Gütern bestimmt unseren Alltag. Materialtransport passiert in globalen Logistikunternehmen, in Fertigungslinien, in alltäglichen Situationen wie dem Einkaufen und selbst in unserem menschlichen Körper. Zu jedem Zeitpunkt werden Materialien von A nach B transportiert, ohne dass uns dies in vielen Situationen bewusst wird. Mit dem Unterschreiten von Größenordnungen im Mikro- und Nanometerbereich wird ein gezielter Materialtransport zu einer Herausforderung, da eine manuelle Manipulation nicht mehr möglich ist. Dennoch wäre es wünschenswert, wenn wir gezielt Material an einen gewünschten Ort transportieren und dort abscheiden könnten, denn diese Lokalisierung wird in vielen Anwendungsfeldern benötigt, um z.B. physikalische Eigenschaften auszunutzen oder chemische oder biologische Reaktionen auszulösen. Daher soll in dieser Arbeit eine Methode zum lokalisierten Materialtransport im Mikro- und Nanometerbereich vorgestellt werden. Diese Methode basiert auf elektrischen Kräften. Einfach ausgedrückt, laden wir ein beliebiges Material elektrisch auf und können es dann in einem elektrischen Feld manipulieren. Negativ geladenes Material wird von negativ geladenen Flächen abgestoßen und von positiv geladenen Flächen angezogen. So lässt sich ein gerichteter Materialtransport erzeugen. Das Material wird mithilfe einer negativen DC Corona-Entladung aufgeladen. Durch die Strukturierung von isolierenden Flächen auf leitfähigen Substraten lassen sich sogenannte elektrodynamische Trichter erzeugen, die das geladene Material zu den gewünschten Orten führen, es dort konzentrieren und abscheiden. Die Nutzung von elektrischen Kräften ermöglicht zudem eine Programmierbarkeit, da durch das Ändern der elektrischen Felder oder durch An- und Ausschalten von Elektroden die Position der Abscheidung, die Abscheideart oder die Abscheiderate geändert werden kann. Die Nutzung der Corona-Entladung ermöglicht eine hohe Freiheit bei der Materialwahl. Die Abscheidung von Metallen, Halbleitern, Isolatoren und biologischen Materialien in einem Größenbereich von Mikropartikeln bis hin zu einzelnen Molekülen wird gezeigt. Die Anwendungsgebiete der vorgestellten Methode sind vielfältig: Sie reichen von Luftüberwachung, Nanodrahtwachstum, Gassensorik bis hin zur Kristallzucht. Die experimentellen Ergebnisse werden mit elektrischen, optischen und materialspezifischen Analysen verifiziert. Darüber hinaus werden Simulationen durchgeführt, um die Art der Lokalisierung zu demonstrieren.
Zahn, Diana; Landers, Joachim; Buchwald, Juliana; Diegel, Marco; Salamon, Soma; Müller, Robert; Köhler, Moritz; Ecke, Gernot; Wende, Heiko; Dutz, Silvio;
Ferrimagnetic large single domain iron oxide nanoparticles for hyperthermia applications. - In: Nanomaterials, ISSN 2079-4991, Bd. 12 (2022), 3, 343, S. 1-12

This paper describes the preparation and obtained magnetic properties of large single domain iron oxide nanoparticles. Such ferrimagnetic particles are particularly interesting for diagnostic and therapeutic applications in medicine or (bio)technology. The particles were prepared by a modified oxidation method of non-magnetic precursors following the green rust synthesis and characterized regarding their structural and magnetic properties. For increasing preparation temperatures (5 to 85 ˚C), an increasing particle size in the range of 30 to 60 nm is observed. Magnetic measurements confirm a single domain ferrimagnetic behavior with a mean saturation magnetization of ca. 90 Am2/kg and a size-dependent coercivity in the range of 6 to 15 kA/m. The samples show a specific absorption rate (SAR) of up to 600 W/g, which is promising for magnetic hyperthermia application. For particle preparation temperatures above 45 ˚C, a non-magnetic impurity phase occurs besides the magnetic iron oxides that results in a reduced net saturation magnetization.
Baloochi, Mostafa; Shekhawat, Deepshikha; Riegler, Sascha Sebastian; Matthes, Sebastian; Glaser, Marcus; Schaaf, Peter; Bergmann, Jean Pierre; Gallino, Isabella; Pezoldt, Jörg;
Influence of initial temperature and convective heat loss on the self-propagating reaction in Al/Ni multilayer foils. - In: Materials, ISSN 1996-1944, Bd. 14 (2021), 24, 7815, insges. 15 S.

A two-dimensional numerical model for self-propagating reactions in Al/Ni multilayer foils was developed. It was used to study thermal properties, convective heat loss, and the effect of initial temperature on the self-propagating reaction in Al/Ni multilayer foils. For model adjustments by experimental results, these Al/Ni multilayer foils were fabricated by the magnetron sputtering technique with a 1:1 atomic ratio. Heat of reaction of the fabricated foils was determined employing Differential Scanning Calorimetry (DSC). Self-propagating reaction was initiated by an electrical spark on the surface of the foils. The movement of the reaction front was recorded with a high-speed camera. Activation energy is fitted with these velocity data from the high-speed camera to adjust the numerical model. Calculated reaction front temperature of the self-propagating reaction was compared with the temperature obtained by time-resolved pyrometer measurements. X-ray diffraction results confirmed that all reactants reacted and formed a B2 NiAl phase. Finally, it is predicted that (1) increasing thermal conductivity of the final product increases the reaction front velocity; (2) effect of heat convection losses on reaction characteristics is insignificant, e.g., the foils can maintain their characteristics in water; and (3) with increasing initial temperature of the foils, the reaction front velocity and the reaction temperature increased.