Publications at the Department of Mathematics and Natural Sciences from 2019

Results: 907
Created on: Mon, 20 May 2024 17:49:54 +0200 in 0.0613 sec


Philipp, Friedrich;
Relatively bounded perturbations of J-non-negative operators. - In: Complex analysis and operator theory, ISSN 1661-8262, Bd. 17 (2023), 1, 14, insges. 30 S.

We improve known perturbation results for self-adjoint operators in Hilbert spaces and prove spectral enclosures for diagonally dominant J-self-adjoint operator matrices. These are used in the proof of the central result, a perturbation theorem for J-non-negative operators. The results are applied to singular indefinite Sturm-Liouville operators with Lp-potentials. Known bounds on the non-real eigenvalues of such operators are improved.



https://doi.org/10.1007/s11785-022-01263-2
Hörsch, Florian; Szigeti, Zoltán
On the complexity of finding well-balanced orientations with upper bounds on the out-degrees. - In: Journal of combinatorial optimization, ISSN 1573-2886, Bd. 45 (2023), 1, 30, S. 1-14

https://doi.org/10.1007/s10878-022-00962-y
Lee, Dae Gwan; Philipp, Friedrich; Voigtlaender, Felix
A note on the invertibility of the Gabor frame operator on certain modulation spaces. - In: The journal of Fourier analysis and applications, ISSN 1531-5851, Bd. 29 (2023), 1, 3, S. 1-20

We consider Gabor frames generated by a general lattice and a window function that belongs to one of the following spaces: the Sobolev space $$V_1 = H^1(\mathbb {R}^d)$$, the weighted $$L^2$$-space $$V_2 = L_{1 + |x|}^2(\mathbb {R}^d)$$, and the space $$V_3 = \mathbb {H}^1(\mathbb {R}^d) = V_1 \cap V_2$$consisting of all functions with finite uncertainty product; all these spaces can be described as modulation spaces with respect to suitable weighted $$L^2$$spaces. In all cases, we prove that the space of Bessel vectors in $$V_j$$is mapped bijectively onto itself by the Gabor frame operator. As a consequence, if the window function belongs to one of the three spaces, then the canonical dual window also belongs to the same space. In fact, the result not only applies to frames, but also to frame sequences.



https://doi.org/10.1007/s00041-022-09980-0
Ilchmann, Achim; Kirchhoff, Jonas
Relative genericity of controllablity and stabilizability for differential-algebraic systems. - In: Mathematics of control, signals, and systems, ISSN 1435-568X, Bd. 35 (2023), 1, S. 45-76

https://doi.org/10.1007/s00498-022-00332-3
Viehweg, Johannes; Worthmann, Karl; Mäder, Patrick
Parameterizing echo state networks for multi-step time series prediction. - In: Neurocomputing, ISSN 1872-8286, Bd. 522 (2023), S. 214-228

Prediction of multi-dimensional time-series data, which may represent such diverse phenomena as climate changes or financial markets, remains a challenging task in view of inherent nonlinearities and non-periodic behavior In contrast to other recurrent neural networks, echo state networks (ESNs) are attractive for (online) learning due to lower requirements w.r.t.training data and computational power. However, the randomly-generated reservoir renders the choice of suitable hyper-parameters as an open research topic. We systematically derive and exemplarily demonstrate design guidelines for the hyper-parameter optimization of ESNs. For the evaluation, we focus on the prediction of chaotic time series, an especially challenging problem in machine learning. Our findings demonstrate the power of a hyper-parameter-tuned ESN when auto-regressively predicting time series over several hundred steps. We found that ESNs’ performance improved by 85.1%-99.8% over an already wisely chosen default parameter initialization. In addition, the fluctuation range is considerably reduced such that significantly worse performance becomes very unlikely across random reservoir seeds. Moreover, we report individual findings per hyper-parameter partly contradicting common knowledge to further, help researchers when training new models.



https://doi.org/10.1016/j.neucom.2022.11.044
Karagianni, Alexandra; Tsierkezos, Nikos; Prato, Maurizio; Terrones, Mauricio; Kordatos, Konstantinos V.
Application of carbon-based quantum dots in photodynamic therapy. - In: Carbon, ISSN 1873-3891, Bd. 203 (2023), S. 273-310

Photodynamic Therapy (PDT) is a non-invasive therapeutic modality that can treat a wide variety of cancer types by means of photosensitizer drug, light, and oxygen. Due to enhanced specificity and fewer side effects, PDT can be an alternative approach for cancer treatments. However, conventional photosensitizers (PSs) exhibit low selectivity, hydrophobicity, and limited photophysical properties. Nanotechnology emerges as a potential solution to these issues and improves PDT efficiency. Nanomaterials such as Carbon Quantum Dots (CQDs) and Graphene Quantum Dots (GrQDs) have been widely applied on PDT research recently, regarding their excellent photoluminescence properties, biocompatibility, as well as their hydrophilicity. The present review article summarizes the main features of PDT and carbon-based quantum dots with an emphasis on used PSs and methods for synthesis of carbon dots. Additionally, the most recent applications of CQDs and GrQDs in PDT have been extensively discussed. The main conclusion that arises is that carbon-based quantum dots seem to be a powerful tool in cancer diagnosis and treatment.



https://doi.org/10.1016/j.carbon.2022.11.026
Nüske, Feliks; Peitz, Sebastian; Philipp, Friedrich; Schaller, Manuel; Worthmann, Karl
Finite-data error bounds for Koopman-based prediction and control. - In: Journal of nonlinear science, ISSN 1432-1467, Bd. 33 (2023), 1, 14, S. 1-34

The Koopman operator has become an essential tool for data-driven approximation of dynamical (control) systems, e.g., via extended dynamic mode decomposition. Despite its popularity, convergence results and, in particular, error bounds are still scarce. In this paper, we derive probabilistic bounds for the approximation error and the prediction error depending on the number of training data points, for both ordinary and stochastic differential equations while using either ergodic trajectories or i.i.d. samples. We illustrate these bounds by means of an example with the Ornstein-Uhlenbeck process. Moreover, we extend our analysis to (stochastic) nonlinear control-affine systems. We prove error estimates for a previously proposed approach that exploits the linearity of the Koopman generator to obtain a bilinear surrogate control system and, thus, circumvents the curse of dimensionality since the system is not autonomized by augmenting the state by the control inputs. To the best of our knowledge, this is the first finite-data error analysis in the stochastic and/or control setting. Finally, we demonstrate the effectiveness of the bilinear approach by comparing it with state-of-the-art techniques showing its superiority whenever state and control are coupled.



https://doi.org/10.1007/s00332-022-09862-1
Wang, Cai; Zheng, Chunfang; Zhao, Huaping; Fu, Qun; Lei, Yong
TiO2 thickness-dependent charge transfer effect in p-aminothiophenol molecules chemisorbed on TiO2/Ni substrates. - In: Applied surface science, Bd. 610 (2023), 155573

Semiconductors have been modulated in thickness to optimize their surface-enhanced Raman scattering (SERS) activity in noble metal/semiconductor SERS substrates. However, the charge transfer (CT) resonance mechanism caused by the change of the semiconductor thickness has not been fully clarified yet, due to the influence of the strong surface plasmon resonance (SPR) effect from the noble metals. Here, systems of p-aminothiophenol (PATP) molecules chemisorbed on TiO2/Ni nanopillar array films with precisely controlled TiO2 thicknesses (PATP/TiO2/Ni) were developed to systematically evaluate the TiO2 thickness-dependent CT mechanism on the premise of minimizing the SPR influence. Ultraviolet-visible, photoluminescence and X-ray photoelectron spectroscopy results demonstrated that four parts that ascribed to the SERS enhancement, photo-induced CT from Ni to TiO2, resonance excitation of TiO2, CT from TiO2 surface states to PATP molecules, and the molecular resonance of PATP molecules, are highly TiO2-thickness dependent. Hence the whole system exhibits a strong TiO2-thickness-dependent CT effect (at the two interfaces of Ni-TiO2 and TiO2-PATP) and SERS activity with a maximum SERS intensity at a TiO2 thickness of 40 nm. This work shall be valuable for future developing an optimal metal/semiconductor SERS substrates and obtaining an in-depth understanding of the semiconductor-thickness-dependent charge transfer mechanism for SERS applications.



https://doi.org/10.1016/j.apsusc.2022.155573
Großmann, Max; Bohm, Sebastian; Heyder, Stefan; Schwarzburg, Klaus; Kleinschmidt, Peter; Runge, Erich; Hannappel, Thomas
Generalized modeling of photoluminescence transients. - In: Physica status solidi, ISSN 1521-3951, Bd. 260 (2023), 1, 2200339, S. 1-12

Time-resolved photoluminescence (TRPL) measurements and the extraction of meaningful parameters involve four key ingredients: a suitable sample such as a semiconductor double heterostructure, a state-of-the-art measurement setup, a kinetic model appropriate for the description of the sample behavior, and a general analysis method to extract the model parameters of interest from the measured TRPL transients. Until now, the last ingredient is limited to single curve fits, which are mostly based on simple models and least-squares fits. These are often insufficient for the parameter extraction in real-world applications. The goal of this article is to give the community a universal method for the analysis of TRPL measurements, which accounts for the Poisson distribution of photon counting events. The method can be used to fit multiple TRPL transients simultaneously using general kinematic models, but should also be used for single transient fits. To demonstrate this approach, multiple TRPL transients of a GaAs/AlGaAs heterostructure are fitted simultaneously using coupled rate equations. It is shown that the simultaneous fits of several TRPL traces supplemented by systematic error estimations allow for a more meaningful and more robust parameter determination. The statistical methods also quantify the quality of the description by the underlying physical model.



https://doi.org/10.1002/pssb.202200339
Wang, Zidong; Hong, Ping; Zhao, Huaping; Lei, Yong
Recent developments and future prospects of transition metal compounds as electrode materials for potassium-ion hybrid capacitors. - In: Advanced Materials Technologies, ISSN 2365-709X, Bd. 8 (2023), 3, 2200515, insges. 18 S.

Potassium-ion hybrid capacitors (PIHCs) have attracted considerable attention as emerging electrochemical energy storage devices for simultaneously achieving high energy and power density, which the key to success is the development of compatible electrode materials for both battery-type anode and capacitive cathode. Among numerous electrode materials, transition metal compounds (including oxides, chalcogenide, carbides, and nitrides) show great potential owing to their high theoretical capacity to achieve high energy density, but their sluggish reaction kinetics restrict the attainable power density. Hence, in the last few years, different strategies are proposed to improve the performance of transition metal compounds as electrode materials for PIHCs, and significant progress is achieved. Herein, this review outlines recent advances of employing transition metal compounds as electrode materials for PIHCs. The performance and challenges of different transition metal compounds are discussed in detail. Finally, the future prospects of practical applications of transition metal compounds in PIHCs are briefly discussed.



https://doi.org/10.1002/admt.202200515