Publications at the Department of Mathematics and Natural Sciences from 2019

Results: 907
Created on: Tue, 14 May 2024 23:06:39 +0200 in 0.0664 sec


Nozdrenko, Dmytro; Matvienko, Tatiana; Vygovska, Oksana; Soroca, Vasil; Bogutska, Kateryna; Zholos, Alexander; Scharff, Peter; Ritter, Uwe; Prylutskyy, Yuriy
Post-traumatic recovery of muscle soleus in rats is improved via synergistic effect of C60 fullerene and TRPM8 agonist menthol. - In: Applied nanoscience, ISSN 2190-5517, Bd. 12 (2022), 3, S. 467-478

Functional biomechanical parameters of muscle soleus contraction in rats as well as selected blood biochemical parameters were studied during the first 3 days of post-traumatic syndrome progression caused by the destruction of muscle cells by compression. Single administration of the antioxidant C60 fullerene and the selective agonist of TRPM8 channels menthol were used as therapeutic agents. Injection of C60 fullerene at a concentration of 1 mg/kg into the damaged muscle improved its contractile function by 25-28%. The use of combined injections of C60 fullerene and menthol (at the concentration 1 mg/kg) improved this index by additional 27-39% and simultaneously stabilized the decrease in muscle strength observed throughout the experiment. A tendency towards a decrease in the indexes of the above described biochemical parameters by 10-15% were found with the therapeutic administration of C60 fullerene. With combined injections of C60 fullerene and menthol, the above described biochemical parameters decreased by an additional 17-24%. The synergism between the action of menthol and C60 fullerene on the post-traumatic recovery of skeletal muscle function opens up new perspectives for the clinical application of this combination therapy.



https://doi.org/10.1007/s13204-021-01703-z
Dong, Yulian; Yan, Chengzhan; Zhao, Huaping; Lei, Yong
Recent advances in 2D heterostructures as advanced electrode materials for potassium-ion batteries. - In: Small structures, ISSN 2688-4062, Bd. 3 (2022), 3, 2100221, insges. 19 S.

Owing to the cost-effectiveness, Earth abundance, and suitable redox potential, potassium-ion batteries (PIBs) stand out as one of the best candidates for large-scale energy storage systems. However, the large radius of K+ and the unsatisfied specific capacity are the main challenges for their commercial applications. To address these challenges, constructing heterostructures by selecting and integrating 2D materials as host and other materials as guest are proposed as an emerging strategy to obtain electrode materials with high capacity and long lifespan, thus improving the energy storage capability of PIBs. Recently, numerous studies are devoted to developing 2D-based heterostructures as electrode materials for PIBs, and significant progress is achieved. However, there is a lack of a review article for systematically summarizing the recent advances and profoundly understanding the relationship between heterostructure electrodes and their performance. In this sense, it is essential to outline the promising advanced features, to summarize the electrochemical properties and performances, and to discuss future research focuses about 2D-based heterostructures in PIBs.



https://doi.org/10.1002/sstr.202100221
Visaveliya, Nikunjkumar R.; Mazétyté-Stasinskiené, Raminta; Köhler, Michael
General background of SERS sensing and perspectives on polymer-supported plasmon-active multiscale and hierarchical sensor particles. - In: Advanced optical materials, ISSN 2195-1071, Bd. 10 (2022), 4, 2102001, S. 1-27

Surface-enhanced Raman scattering (SERS) is one of the most powerful analytical techniques for the identification of molecules. The substrate, on which SERS is dependent, contains regions of nanoscale gaps (hotspots) that hold the ability to concentrate incident electromagnetic fields and effectively amplify vibrational scattering signals of adsorbed analytes. While surface plasmon resonance from metal nanostructures is a central focus for the SERS effect, the support of polymers can be significantly advantageous to provide larger exposure of structured metal surfaces for efficient interactions with analytes. Characteristics of the polymer particles such as softness, flexibility, swellability, porosity, optical transparency, metal-loading ability, and high surface area can allow diffusion of analytes and penetrating light deeply that can enormously amplify sensing outcomes. As polymer-supported plasmon-active sensor particles can emerge as versatile SERS substrates, the microfluidic platform is promising for the generation of sensor particles as well as for performing sequential SERS analysis of multiple analytes. Therefore, in this perspective article, the development of multifunctional polymer-metal composite particles, and their applications as potential sensors for SERS sensing through microfluidics are presented. A detailed background from the beginning of the SERS field and perspectives for the multifunctional sensor particles for efficient SERS sensing are provided.



https://doi.org/10.1002/adom.202102001
Hülser, Tobias; Köster, Felix; Jaurigue, Lina; Lüdge, Kathy
Role of delay-times in delay-based photonic reservoir computing. - In: Optical materials express, ISSN 2159-3930, Bd. 12 (2022), 3, S. 1214-1231

Delay-based reservoir computing has gained a lot of attention due to the relative simplicity with which this concept can be implemented in hardware. However, unnecessary constraints are commonly placed on the relationship between the delay-time and the input clock-cycle, which can have a detrimental effect on the performance. We review the existing literature on this subject and introduce the concept of delay-based reservoir computing in a manner that demonstrates that no predefined relationship between the delay-time and the input clock-cycle is required for this computing concept to work. Choosing the delay-times independent of the input clock-cycle, one gains an important degree of freedom. Consequently, we discuss ways to improve the computing performance of a reservoir formed by delay-coupled oscillators and show the impact of delay-time tuning in such systems.



https://doi.org/10.1364/OME.451016
Karmo, Marsel; Ruiz Alvarado, Isaac Azahel; Schmidt, W. Gero; Runge, Erich
Reconstructions of the As-terminated GaAs(001) surface exposed to atomic hydrogen. - In: ACS omega, ISSN 2470-1343, Bd. 7 (2022), 6, S. 5064-5068

We explore the atomic structures and electronic properties of the As-terminated GaAs(001) surface in the presence of hydrogen based on ab initio density functional theory. We calculate a phase diagram dependent on the chemical potentials of As and H, showing which surface reconstruction is the most stable for a given set of chemical potentials. The findings are supported by the calculation of energy landscapes of the surfaces, which indicate possible H bonding sites as well as the density of states, which show the effect of hydrogen adsorption on the states near the fundamental band gap.



https://doi.org/10.1021/acsomega.1c06019
Nozdrenko, Dmytro; Prylutska, Svitlana; Bogutska, Kateryna; Nurishchenko, Natalia Y.; Abramchuk, Olga; Motuziuk, Olexandr; Prylutskyy, Yuriy; Scharff, Peter; Ritter, Uwe
Effect of C60 fullerene on recovery of muscle soleus in rats after atrophy induced by achillotenotomy. - In: Life, ISSN 2075-1729, Bd. 12 (2022), 3, 332, S. 1-13

Biomechanical and biochemical changes in the muscle soleus of rats during imitation of hind limbs unuse were studied in the model of the Achilles tendon rupture (Achillotenotomy). Oral administration of water-soluble C60 fullerene at a dose of 1 mg/kg was used as a therapeutic agent throughout the experiment. Changes in the force of contraction and the integrated power of the muscle, the time to reach the maximum force response, the mechanics of fatigue processes development, in particular, the transition from dentate to smooth tetanus, as well as the levels of pro- and antioxidant balance in the blood of rats on days 15, 30 and 45 after injury were described. The obtained results indicate a promising prospect for C60 fullerene use as a powerful antioxidant for reducing and correcting pathological conditions of the muscular system arising from skeletal muscle atrophy.



https://doi.org/10.3390/life12030332
Ilchmann, Achim; Witschel, Jonas; Worthmann, Karl
Model predictive control for singular differential-algebraic equations. - In: International journal of control, ISSN 1366-5820, Bd. 95 (2022), 8, S. 2141-2150

We study model predictive control for singular differential-algebraic equations with higher index. This is a novelty when compared to the literature where only regular differential-algebraic equations with additional assumptions on the index and/or controllability are considered. By regularisation techniques, we are able to derive an equivalent optimal control problem for an ordinary differential equation to which well-known model predictive control techniques can be applied. This allows the construction of terminal constraints and costs such that the origin is asymptotically stable w.r.t. the resulting closed-loop system.



https://doi.org/10.1080/00207179.2021.1900604
Mytiliniou, Maria; Wondergem, Joeri A. J.; Schmidt, Thomas; Heinrich, Doris
Impact of neurite alignment on organelle motion. - In: Interface, ISSN 1742-5662, Bd. 19 (2022), 187, 20210617, S. 1-13

Intracellular transport is pivotal for cell growth and survival. Malfunctions in this process have been associated with devastating neurodegenerative diseases, highlighting the need for a deeper understanding of the mechanisms involved. Here, we use an experimental methodology that leads neurites of differentiated PC12 cells into either one of two configurations: a one-dimensional configuration, where the neurites align along lines, or a two-dimensional configuration, where the neurites adopt a random orientation and shape on a flat substrate. We subsequently monitored the motion of functional organelles, the lysosomes, inside the neurites. Implementing a time-resolved analysis of the mean-squared displacement, we quantitatively characterized distinct motion modes of the lysosomes. Our results indicate that neurite alignment gives rise to faster diffusive and super-diffusive lysosomal motion than the situation in which the neurites are randomly oriented. After inducing lysosome swelling through an osmotic challenge by sucrose, we confirmed the predicted slowdown in diffusive mobility. Surprisingly, we found that the swelling-induced mobility change affected each of the (sub-/super-)diffusive motion modes differently and depended on the alignment configuration of the neurites. Our findings imply that intracellular transport is significantly and robustly dependent on cell morphology, which might in part be controlled by the extracellular matrix.



https://doi.org/10.1098/rsif.2021.0617
Bang-Jensen, Jørgen; Havet, Frederic; Kriesell, Matthias; Yeo, Anders
Low chromatic spanning sub(di)graphs with prescribed degree or connectivity properties. - In: Journal of graph theory, ISSN 1097-0118, Bd. 99 (2022), 4, S. 615-636

https://doi.org/10.1002/jgt.22755
Gao, Yueyue; Cui, Minghuan; Qu, Shengchun; Zhao, Huaping; Shen, Zhitao; Tan, Furui; Dong, Yulian; Qin, Chaochao; Wang, Zhijie; Zhang, Weifeng; Wang, Zhangguo; Lei, Yong
Efficient organic solar cells enabled by simple non-fused electron donors with low synthetic complexity. - In: Small, ISSN 1613-6829, Bd. 18 (2022), 3, 2104623, insges. 10 S.

https://doi.org/10.1002/smll.202104623