Publications at the Department of Mathematics and Natural Sciences from 2019

Results: 900
Created on: Mon, 29 Apr 2024 16:43:17 +0200 in 0.0578 sec


Rußwurm, Franz; Esterhuizen, Willem; Worthmann, Karl; Streif, Stefan
On MPC without terminal conditions for dynamic non-holonomic robots. - In: IFAC-PapersOnLine, ISSN 2405-8963, Bd. 54 (2021), 6, S. 133-138

We consider an input-constrained differential-drive robot with actuator dynamics. For this system, we establish asymptotic stability of the origin on arbitrary compact, convex sets using Model Predictive Control (MPC) without stabilizing terminal conditions despite the presence of state constraints and actuator dynamics. We note that the problem without those two additional ingredients was essentially solved beforehand, despite the fact that the linearization is not stabilizable. We propose an approach successfully solving the task at hand by combining the theory of barriers to characterize the viability kernel and an MPC framework based on so-called cost controllability. Moreover, we present a numerical case study to derive quantitative bounds on the required length of the prediction horizon. To this end, we investigate the boundary of the viability kernel and a neighbourhood of the origin, i.e. the most interesting areas.



https://doi.org/10.1016/j.ifacol.2021.08.535
Schütt, Timo; Geitner, Robert; Bode, Stefan; Schubert, Ulrich Sigmar
Dialysis diffusion kinetics in polymer purification. - In: Macromolecules, ISSN 1520-5835, Bd. 54 (2021), 20, S. 9410-9417

Diffusion kinetics of a prior developed automated dialysis system are investigated via in situ NMR spectroscopy for an optimization of conventional and advanced polymer purification. Using a polymeric solution, mixed with the respective monomer, several parameters like starting concentration, solvent volume, and solvent exchange by flow or complete one-time exchange are varied, resulting in a significant decrease of purification time for the automated setup. With an increased solvent flow (from 0.9 to 5.5 mL/min), 5.4 h and 2000 mL of solvent are required to decrease the monomer concentration to the detection limit. Without solvent flow, which corresponds to conventional dialysis, only 9 h and 250 mL of solvent are required for the same result, which is a time- and solvent-saving development for common purification of polymers.



https://doi.org/10.1021/acs.macromol.1c01241
Kronfeld, Klaus-Peter; Mazétyté-Stasinskiené, Raminta; Zheng, Xuejiao; Köhler, Michael
Textured and hierarchically constructed polymer micro- and nanoparticles. - In: Applied Sciences, ISSN 2076-3417, Bd. 11 (2021), 21, 10421, S. 1-17

Microfluidic techniques allow for the tailored construction of specific microparticles, which are becoming increasingly interesting and relevant. Here, using a microfluidic hole-plate-device and thermal-initiated free radical polymerization, submicrometer polymer particles with a highly textured surface were synthesized. Two types of monomers were applied: (1) methylmethacrylate (MMA) combined with crosslinkers and (2) divinylbenzene (DVB). Surface texture and morphology can be influenced by a series of parameters such as the monomer-crosslinker-solvent composition, surfactants, and additives. Generally, the most structured surfaces with the simultaneously most uniform particles were obtained in the DVB-toluene-nonionic-tensides system. In a second approach, poly-MMA (PMMA) particles were used to build aggregates with bigger polymer particles. For this purpose, tripropyleneglycolediacrylate (TPGDA) particles were synthesized in a microfluidic co-flow arrangement and polymerized by light- irradiation. Then, PMMA particles were assembled at their surface. In a third step, these composites were dispersed in an aqueous acrylamide-methylenebisacrylamide solution, which again was run through a co-flow-device and photopolymerized. As such, entities consisting of particles of three different size ranges - typically 0.7/30/600 [my]m - were obtained. The particles synthesized by both approaches are potentially suitable for loading with or incorporation of analytic probes or catalysts such as dyes or metals.



https://doi.org/10.3390/app112110421
Schweser, Thomas; Stiebitz, Michael
Vertex partition of hypergraphs and maximum degenerate subhypergraphs. - In: Electronic Journal of Graph Theory and Applications, ISSN 2338-2287, Bd. 9 (2021), 1, S. 1-9

https://doi.org/10.5614/ejgta.2021.9.1.1
Sha, Mo; Zhao, Huaping; Lei, Yong
Updated insights into 3D architecture electrodes for micropower sources. - In: Advanced materials, ISSN 1521-4095, Bd. 33 (2021), 45, 2103304, insges. 17 S.

Microbatteries (MBs) and microsupercapacitors (MSCs) are primary on-chip micropower sources that drive autonomous and stand-alone microelectronic devices for implementation of the Internet of Things (IoT). However, the performance of conventional MBs and MSCs is restricted by their 2D thin-film electrode design, and these devices struggle to satisfy the increasing IoT energy demands for high energy density, high power density, and long lifespan. The energy densities of MBs and MSCs can be improved significantly through adoption of a 2D thick-film electrode design; however, their power densities and lifespans deteriorate with increased electrode thickness. In contrast, 3D architecture electrodes offer remarkable opportunities to simultaneously improve MB and MSC energy density, power density, and lifespan. To date, various 3D architecture electrodes have been designed, fabricated, and investigated for MBs and MSCs. This review provides an update on the principal superiorities of 3D architecture electrodes over 2D thick-film electrodes in the context of improved MB and MSC energy density, power density, and lifespan. In addition, the most recent and representative progress in 3D architecture electrode development for MBs and MSCs is highlighted. Finally, present challenges are discussed and key perspectives for future research in this field are outlined.



https://doi.org/10.1002/adma.202103304
Liang, Feng; Zhang, Kaiwen; Zhang, Lei; Zhang, Yingjie; Lei, Yong; Sun, Xueliang
Recent development of electrocatalytic CO2 reduction application to energy conversion. - In: Small, ISSN 1613-6829, Bd. 17 (2021), 44, 2100323, insges. 29 S.
Im Titel ist "2" tiefgestellt

Carbon dioxide (CO2) emission has caused greenhouse gas pollution worldwide. Hence, strengthening CO2 recycling is necessary. CO2 electroreduction reaction (CRR) is recognized as a promising approach to utilize waste CO2. Electrocatalysts in the CRR process play a critical role in determining the selectivity and activity of CRR. Different types of electrocatalysts are introduced in this review: noble metals and their derived compounds, transition metals and their derived compounds, organic polymer, and carbon-based materials, as well as their major products, Faradaic efficiency, current density, and onset potential. Furthermore, this paper overviews the recent progress of the following two major applications of CRR according to the different energy conversion methods: electricity generation and formation of valuable carbonaceous products. Considering electricity generation devices, the electrochemical properties of metal-CO2 batteries, including Li-CO2, Na-CO2, Al-CO2, and Zn-CO2 batteries, are mainly summarized. Finally, different pathways of CO2 electroreduction to carbon-based fuels is presented, and their reaction mechanisms are illustrated. This review provides a clear and innovative insight into the entire reaction process of CRR, guiding the new electrocatalysts design, state-of-the-art analysis technique application, and reaction system innovation.



https://doi.org/10.1002/smll.202100323
Schaller, Manuel; Philipp, Friedrich; Faulwasser, Timm; Worthmann, Karl; Maschke, Bernhard
Control of port-Hamiltonian systems with minimal energy supply. - In: European journal of control, ISSN 1435-5671, Bd. 62 (2021), S. 33-40

We investigate optimal control of linear port-Hamiltonian systems with control constraints, in which one aims to perform a state transition with minimal energy supply. Decomposing the state space into dissipative and non-dissipative (i.e. conservative) subspaces, we show that the set of reachable states is bounded w.r.t. the dissipative subspace. We prove that the optimal control problem exhibits the turnpike property with respect to the non-dissipative subspace, i.e., for varying initial conditions and time horizons optimal state trajectories evolve close to the conservative subspace most of the time. We analyze the corresponding steady-state optimization problem and prove that all optimal steady states lie in the non-dissipative subspace. We conclude this paper by illustrating these results by a numerical example from mechanics.



https://doi.org/10.1016/j.ejcon.2021.06.017
Marx-Blümel, Lisa; Marx, Christian; Sonnemann, Jürgen; Weise, Frank; Hampl, Jörg; Frey, Jessica; Rothenburger, Linda; Cirri, Emilio; Rahnis, Norman; Koch, Philipp; Groth, Marco; Schober, Andreas; Wang, Zhao-Qi; Beck, James F.
Molecular characterization of hematopoietic stem cells after in vitro amplification on biomimetic 3D PDMS cell culture scaffolds. - In: Scientific reports, ISSN 2045-2322, Bd. 11 (2021), 21163, S. 1-14

Hematopoietic stem cell (HSC) transplantation is successfully applied since the late 1950s. However, its efficacy can be impaired by insufficient numbers of donor HSCs. A promising strategy to overcome this hurdle is the use of an advanced ex vivo culture system that supports the proliferation and, at the same time, maintains the pluripotency of HSCs. Therefore, we have developed artificial 3D bone marrow-like scaffolds made of polydimethylsiloxane (PDMS) that model the natural HSC niche in vitro. These 3D PDMS scaffolds in combination with an optimized HSC culture medium allow the amplification of high numbers of undifferentiated HSCs. After 14 days in vitro cell culture, we performed transcriptome and proteome analysis. Ingenuity pathway analysis indicated that the 3D PDMS cell culture scaffolds altered PI3K/AKT/mTOR pathways and activated SREBP, HIF1α and FOXO signaling, leading to metabolic adaptations, as judged by ELISA, Western blot and metabolic flux analysis. These molecular signaling pathways can promote the expansion of HSCs and are involved in the maintenance of their pluripotency. Thus, we have shown that the 3D PDMS scaffolds activate key molecular signaling pathways to amplify the numbers of undifferentiated HSCs ex vivo effectively.



https://doi.org/10.1038/s41598-021-00619-6
Espuny Díaz, Alberto; Girão, António
Hamiltonicity of randomly perturbed graphs. - In: Extended abstracts EuroComb 2021, (2021), S. 38-44

The theory of randomly perturbed graphs deals with the properties of graphs obtained as the union of a deterministic graph H and a random graph G. We study Hamiltonicity in two distinct settings. In both of them, we assume H is some deterministic graph with minimum degree at least αn, for some α (possibly depending on n). We first consider the case when G is a random geometric graph, and obtain an asymptotically optimal result. We then consider the case when G is a random regular graph, and obtain different results depending on the regularity.



Espuny Díaz, Alberto; Patel, Viresh; Stroh, Fabian
Path decompositions of random directed graphs. - In: Extended abstracts EuroComb 2021, (2021), S. 702-706

In this work we consider extensions of a conjecture due to Alspach, Mason, and Pullman from 1976. This conjecture concerns edge decompositions of tournaments into as few paths as possible. There is a natural lower bound for the number paths needed in an edge decomposition of a directed graph in terms of its degree sequence; the conjecture in question states that this bound is correct for tournaments of even order. The conjecture was recently resolved for large tournaments, and here we investigate to what extent the conjecture holds for directed graphs in general. In particular, we prove that the conjecture holds with high probability for the random directed graph Dn,pDn,pD_{n,p} for a large range of p.