Monographs from 2018

Results: 697
Created on: Tue, 23 Jul 2024 23:02:34 +0200 in 0.0454 sec


Yan, Yong; Li, Tongxian; Oliva Ramírez, Manuel; Zhao, Yuguo; Wang, Shuo; Chen, Xin; Wang, Dong; Schaaf, Peter; Wang, Xiayan; Guo, Guangsheng
Efficient tuning of the selectivity of Cu-based interface for electrocatalytic CO2 reduction by ligand modification. - In: Materials today, ISSN 2468-6069, Bd. 44 (2024), 101620, S. 1-12

The development of efficient strategies to tune the CO2RR selectivity of Cu-based catalytic interfaces, especially on specific domains, such as Cu (200) facets with high activity toward competitive hydrogenation evolution reaction (HER), remains a challenging task. In this work, Cu-based catalytic layers with thiocyanate (-SCN), cyanide (-CN), or ethylenediamine (-NH2R) coordination linkages are prepared on Cu nanocolumns arrays (Cu NCAs) with predominant (200) exposed facets. The coordination of these ligands induces more Cu+ species and inhibits the adsorption of H∗ on the Cu (200) facet, leading to enhanced CO2RR performance and substantially suppressing the competitive HER. The faradaic efficiency (FE) of Cu–SCN, Cu–CN, and Cu–NH2R NWAs for producing HCOOH, C2H4, and C1 mixture products (HCOOH and CO) reach to 66.5%, 21.1%, and 57.1%, respectively. In situ spectroscopic studies reveal Cu–SCN, Cu–CN, and Cu–NH2R exhibit more reasonable adsorption energy toward ∗OCHO, ∗CO, and ∗COOH intermediates, promoting the HCOOH, C2H4, and C1 mixture generation, respectively. This study might provide a new perspective for the development of high-performance Cu-based CO2RR catalytic electrodes based on the combination of various commercial free-standing Cu substrates and organic/inorganic ligands.



https://doi.org/10.1016/j.mtener.2024.101620
Sauni Camposano, Yesenia Haydee; Jaekel, Konrad; Riegler, Sascha S.; Matthes, Sebastian; Glaser, Marcus; Peter, Nicolas J.; Vardo, Emina; Bartsch, Heike; Schwaiger, Ruth; Bergmann, Jean Pierre; Gallino, Isabella; Schaaf, Peter
Controlling propagation velocity in Al/Ni reactive multilayer systems by periodic 2D surface structuring. - In: Advanced engineering materials, ISSN 1527-2648, Bd. n/a (2024), n/a, 2302272, S. 1-11

The chemical energy released as heat during the exothermic reaction of reactive multilayer systems has shown potential applications in various technological areas, e.g., in joining applications. However, controlling the heat release rate and the propagation velocity of the reaction is required to enhance their performance in most of these applications. Herein, a method to control the propagation velocity and heat release rate of the system is presented. The sputtering of Al/Ni multilayers on substrates with periodic 2D surface structures promotes the formation of growth defects into the system. This modification in the morphology locally influences the reaction characteristics. Tailoring the number of 2D structures in the substrate enables the control of the velocity and maximum temperature of the propagation front. The morphology of the produced reactive multilayers is investigated before and after reaction using scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. In addition, the enthalpy of the system is obtained through calorimetric analysis. The self-sustained and self-propagating reaction of the systems is monitored by a high-speed camera and a high-speed pyrometer, thus revealing the propagation velocity and the temperatures with time resolution in the microsecond regime.



https://doi.org/10.1002/adem.202302272
Graske, Marcus; Sauni Camposano, Yesenia Haydee; Vardo, Emina; Matthes, Sebastian; Schaaf, Peter
Mechanical ignition of Al/Ni reactive multilayer systems: influence of impacting material, its properties, and geometric characteristics. - In: Advanced engineering materials, ISSN 1527-2648, Bd. n/a (2024), n/a, 2400479, S. 1-13

Al/Ni reactive multilayer systems (RMS) with a bilayer thickness of Λ = 50 nm and total thickness th = 5 μm on a SiO2 substrate exhibit a self-propagating reaction after ignition. A common method to initiate the self-propagating reaction is by electric spark ignition. Herein, RMS are ignited by a mechanical impact using various materials with indeterminate geometries to investigate the basic mechanisms. SiO2, glass, PMMA, and resin-bonded SiC particles are used as impacting material with different geometrical impact areas. The used materials are placed on top of the RMS and a mechanical impulse is applied. The ignition behavior of the RMS is subsequently evaluated and classified. Additionally, the impacted RMS are examined by microscopy to reveal the damage pattern. By correlating particle size ⟨Dparticle⟩ and spacing ⟨dhole⟩ of the penetrating materials, an ignition threshold can be established. Moreover, the results demonstrate that the energy input threshold can be reduced through a strategic distribution of particles within the impacting and penetrating geometry. This provides valuable insights into the mechanical ignition fundamental and supports future applications of mechanical ignition of RMS.



https://doi.org/10.1002/adem.202400479
Wang, Honglei; Cheng, Pengfei; Wu, Bing; Yan, Yong; Schaaf, Peter; Sofer, Zdeněk; Wang, Dong
2D metal phosphorous trichalcogenides (MPCh3) for sustainable energy storage and conversion: nanoarchitectonics and advanced applications. - In: Advanced functional materials, ISSN 1616-3028, Bd. n/a (2024), n/a, 2407432, S. 1-22

2D metal phosphorous trichalcogenides (MPCh3) have attracted considerable attention in sustainable energy storage and conversion due to their distinct physical and chemical characteristics, such as adjustable energy bandgap, significant specific surface area, and abundant active sites. However, research on 2D MPCh3 primarily focuses on electrocatalysis, and understanding its energy conversion and storage mechanisms remains incomplete. This review comprehensively summarizes recent advancements in energy storage and conversion using 2D MPCh3-based materials of various structures. It begins with a discussion of the distinctive properties and preparation techniques of 2D MPCh3, followed by a focus on the rational design and development of these materials for diverse energy-related applications, including rechargeable batteries, supercapacitors, electrocatalysis, photocatalysis, and desalination. Finally, it outlines the key challenges and prospects for future research on 2D MPCh3 materials.



https://doi.org/10.1002/adfm.202407432
Vardo, Emina; Sauni Camposano, Yesenia Haydee; Matthes, Sebastian; Glaser, Marcus; Bartsch, Heike; Hildebrand, Jörg; Bergmann, Jean Pierre; Schaaf, Peter
Impact of substrate thickness and surface roughness on Al/Ni multilayer reaction kinetics. - In: Advanced engineering materials, ISSN 1527-2648, Bd. n/a (2024), n/a, 2302269, S. 1-10

Reactive multilayers comprising alternating nanoscale layers of Al and Ni exhibit potential across various applications, including localized heating for welding and joining. Control over reaction properties is pivotal for emerging applications, such as chemical time delays or neutralization of biological or chemical weapons. In this research, insights are offered into the intricate interplay between substrate thickness, surface roughness, and the behavior of Al/Ni reactive multilayers, opening avenues for tailored applications in various domains. To observe this interplay, silica with various thicknesses from 0.4 to 1.6 μm is deposited on polished single-crystalline Si and rough poly-Si base substrates. Additionally, to analyze the impact of varying silica thickness along the sample length on reaction behavior, silica in steplike shape is fabricated. Subsequently, Al/Ni multilayers with 5 μm total thickness and 20 or 50 nm bilayer periodicities are deposited. Reaction velocity and temperature are monitored with a high-speed camera and pyrometer. In the results, it is indicated that silica thickness significantly affects self-propagation in multilayers. The reaction is not self-sustained for silica layers ≤ 0.4 μm, depending on bilayer periodicity and substrate roughness. The velocity increases or decreases based on the direction of reaction propagation, whether it moves upward or downward, in relation to the thickness of silica.



https://doi.org/10.1002/adem.202302269
Riegler, Sascha S.; Sauni Camposano, Yesenia Haydee; Jaekel, Konrad; Frey, Maximilian; Neemann, Christian; Matthes, Sebastian; Vardo, Emina; Chegeni, Maryam R.; Bartsch, Heike; Busch, Ralf; Müller, Jens; Schaaf, Peter; Gallino, Isabella
Nanocalorimetry of nanoscaled Ni/Al multilayer films: on the methodology to determine reaction kinetics for highly reactive films. - In: Advanced engineering materials, ISSN 1527-2648, Bd. 0 (2024), 0, 2302279, S. 1-10

Free-standing Ni/Al multilayer films with a planar morphology, a bilayer thickness of 20 nm, and an average composition of Ni50Al50 (at%) deposited by direct current magnetron sputtering are investigated by nanocalorimetry and conventional calorimetry. Both the novel fast differential scanning calorimeter (FDSC) Flash DSC 2+ from Mettler-Toledo (MT) and conventional calorimeter MT DSC 3 are used to cover a range of heating rates from 0.1 to 10^4 K s^−1. A quantitative kinetic study of the interdiffusion and phase reaction sequence is performed via a Kissinger analysis covering five orders of magnitude of heating rates. Using the calorimetric data, the derived apparent activation energies suggest monotonic reaction kinetics over the entire range of heating rates applied. To correct the thermal lag at the highest heating rates with the FDSC for nonadhered free-standing films, a new methodology for its correction is used. Overall, this work extends the application of commercial FDSC to nonadhered films.



https://doi.org/10.1002/adem.202302279
Smyrnova, Kateryna; Sahul, Martin; Haršáni, Marián; Beresnev, Vyacheslav; Truchlý, Martin; Čaplovič, L’ubomír; Čaplovičová, Mária; Kusý, Martin; Kozak, Andrii; Flock, Dominik; Kassymbaev, Alexey; Pogrebnjak, Aleksandr Dmitrievič
Composite materials with nanoscale multilayer architecture based on cathodic-arc evaporated WN/NbN coatings. - In: ACS omega, ISSN 2470-1343, Bd. 9 (2024), 15, S. 17247-17265

Hard nitride coatings are commonly employed to protect components subjected to friction, whereby such coatings should possess excellent tribomechanical properties in order to endure high stresses and temperatures. In this study, WN/NbN coatings are synthesized by using the cathodic-arc evaporation (CA-PVD) technique at various negative bias voltages in the 50-200 V range. The phase composition, microstructural features, and tribomechanical properties of the multilayers are comprehensively studied. Fabricated coatings have a complex structure of three nanocrystalline phases: β-W2N, δ-NbN, and ε-NbN. They demonstrate a tendency for (111)-oriented grains to overgrow (200)-oriented grains with increasing coating thickness. All of the data show that a decrease in the fraction of ε-NbN phase and formation of the (111)-textured grains positively impact mechanical properties and wear behavior. Investigation of the room-temperature tribological properties reveals that with an increase in bias voltage from −50 to −200 V, the wear mechanisms change as follows: oxidative &flech; fatigue and oxidative &flech; adhesive and oxidative. Furthermore, WN/NbN coatings demonstrate a high hardness of 33.6-36.6 GPa and a low specific wear rate of (1.9-4.1) × 10-6 mm3/Nm. These results indicate that synthesized multilayers hold promise for tribological applications as wear-resistant coatings.



https://doi.org/10.1021/acsomega.3c10242
Zhao, Yuguo; Björk, Emma M.; Yan, Yong; Schaaf, Peter; Wang, Dong
Recent progress in transition metal based catalysts and mechanism analysis for alcohol electrooxidation reactions. - In: Green chemistry, ISSN 1463-9270, Bd. 26 (2024), 9, S. 4987-5003

In order to address energy and environmental challenges effectively, there is a need to promote renewable energy-driven electrochemical conversion technologies, particularly electrosynthesis. Electrosynthesis has the potential to convert abundant molecules into valuable chemicals and fuels. However, the widespread adoption of electrosynthesis is often hindered by the slow oxygen evolution reaction (OER). To overcome this limitation, we can employ the more efficient alcohol electrooxidation reaction (AOR), utilizing renewable biomass-derived alcohols as an alternative to OER for producing high-value chemicals. Consequently, the development of efficient AOR catalysts, in conjunction with cathodic reduction reactions (hydrogen evolution, oxygen, and nitrogen electroreduction, etc.), is crucial for sustainable and environmentally-friendly advancements. A thorough understanding of AOR mechanisms is essential for catalyst design and can be achieved through the utilization of in situ characterization techniques and density functional theory (DFT) calculations. This review summarizes recent progress in AOR catalysts, with a particular focus on the electrooxidation of monohydric alcohols, polyols, and associated studies on reaction mechanisms. Additionally, the review identifies key factors impeding AOR development and provides insights into future prospects.



https://doi.org/10.1039/D4GC00227J
Jaekel, Konrad; Riegler, Sascha Sebastian; Sauni Camposano, Yesenia Haydee; Matthes, Sebastian; Glaser, Marcus; Bergmann, Jean Pierre; Schaaf, Peter; Gallino, Isabella; Müller, Jens; Bartsch, Heike
Influence of increasing density of microstructures on the self-propagating reaction of Al/Ni reactive nanoscale multilayers. - In: Advanced engineering materials, ISSN 1527-2648, Bd. 0 (2024), 0, insges. 21 S.

Surface structuring methods are crucial in semiconductor manufacturing, as they enable the creation of intricate structures on the semiconductor surface, influencing the material’s electrical, mechanical, and chemical properties. This study employs one such structuring method known as reactive ion etching to create black Si structures on silicon substrates. After thermal oxidation, their influence on the reaction of Al/Ni nanoscale multilayers is. For this purpose, various densities of thermally oxidized black Si structures are investigated. It reveals distinct reactive behaviors without corresponding differences in energy release during differential scanning calorimetry measurements. Higher oxidized black Si structure densities result in elevated temperatures and faster reaction propagation, showing fewer defects and reduced layer connections in cross-sectional analyses. The properties of the reactive multilayers on high structure density show the same performance as a reaction on flat thermal SiO2, causing delamination when exceeding 23 structures per µm2. Conversely, lower structure density ensures attachment of reactive multilayers to the substrate due to an increased number of defects, acting as predetermined breaking points for the AlNi alloy. By establishing the adhesion between the reacted multilayer and the substrate, surface structuring could lead to a potential increase in bond strength when using reactive multilayers for bonding.



https://doi.org/10.1002/adem.202302225
Matthes, Sebastian; Glaser, Marcus; Vardo, Emina; Sauni Camposano, Yesenia Haydee; Jaekel, Konrad; Bergmann, Jean Pierre; Schaaf, Peter
Tailoring the reaction path: external crack initiation in reactive Al/Ni multilayers. - In: Advanced engineering materials, ISSN 1527-2648, Bd. 0 (2024), 0, 2302271, S. 1-6

The influence of intentionally externally induced cracks in reactive Al/Ni multilayer systems is investigated. These cracks affect the reaction dynamics and enable tailoring of the reaction path and the overall velocity of the reaction front. The influence of layer variations onto mechanical crack formation and resulting reaction behavior are investigated. High-speed camera imaging shows the meandering propagation of the reaction front along the crack paths. Therefore, the mechanical cracking process significantly changes the total velocity of the reaction front and thus offers a possibility to control the self-propagating high-temperature synthesis process. It is shown that the phase formation remains unaffected despite the applied strains and cracks. This favorable stability in phase formation ensures predictability and provides insight into the adaptation of RMS for precision applications in joints. The results expand the understanding of mechanical cracking as a tool to influence high-temperature synthesis in reactive multilayer coatings and provide an opportunity to expand the range of applications.



https://doi.org/10.1002/adem.202302271