Preface magnetic carriers conference 2018. - In: Journal of magnetism and magnetic materials, ISSN 1873-4766, Bd. 494 (2020), 165748
https://doi.org/10.1016/j.jmmm.2019.165748
Active scanning probes in nanostructure fabrication. - In: Design strategies for synthesis and fabrication, (2020), S. 18-1-18-12
Richtiger Name des Verfassers: Mathias Holz
https://dx.doi.org/10.1201/9780367341558-18
Anwendungen der Schwingquarzmethode in der Galvanotechnik. - In: ZVO-Report, (2020), 2, S. 42
Abscheidung von dekorativen Chromschichten mittels niederfrequenter Pulsabscheidung zur Anpassung des optischen Erscheinungsbilds. - In: WOMag, ISSN 2195-5905, Bd. 9 (2020), 6, S. 1-8
Das optische Erscheinungsbild von galvanisch abgeschiedenen Chromschichten ist eines der wichtigsten Kriterien für deren dekorative Anwendung. Für die dekorative Verchromung werden zunehmend Elektrolyte auf Basis von dreiwertigem Chrom als Ersatz für die bisher verwendeten Elektrolyte auf Basis von sechswertigem Chrom eingesetzt. Chrom aus Elektrolyten mit dreiwertigen Chromverbindungen neigt jedoch dazu, bei Dicken über 100 nm einen gelblichen Farbton zu haben, was für die meisten Anwendungen unerwünscht ist. Die Farbverschiebung hängt mit einer Änderung der Oberflächenmorphologie aufgrund des Wachstums der Chromkeime zusammen. Durch die Verwendung von gepulstem Strom mit Einschaltzeiten im Bereich von Sekunden wird das unerwünschte Kornwachstum unterdrückt und die Bildung frischer Kerne begünstigt. Dadurch bilden sich kompakte Chromschichten mit feinerem Gefüge und verbesserten Farbwerten. Ein bläuliches Aussehen und ein hoher Glanz werden bis zu einer Dicke von mehr als 200 nm beibehalten. Basierend auf den Ergebnissen wird eine Kombination aus konstantem und gepulstem Strom vorgeschlagen, die ein ähnliches visuelles Erscheinungsbild ergibt wie nur bei gepulstem Strom, jedoch die angestrebte Schichtdicke in deutlich kürzerer Zeit erreicht.
https://dx.doi.org/10.7395/2020/Leimbach1
Synthesis and characterization of size controlled bimetallic nanosponges. - In: Multifunctional materials, (2020), S. 1-34
Metallic and bimetallic nanosponges with well-defined size and form have attracted increasing attention due to their unique structural properties and their potential for many applications. In this chapter, the recently developed methods for the synthesis and preparation of metallic and bimetallic nanosponges are presented. These methods can be mainly cataloged in two groups: dealloying-based methods and reduction reaction-based methods. Different topographical reconstruction methods for the investigation of their structural properties are then reviewed briefly. The optical properties of the metallic nanosponges are clearly different from those of the solid counterparts due to the tailored disordered structure. The recent advances in the exploration of the distinct linear and non-linear optical properties of the nanosponges are summarized.
https://doi.org/10.1515/9783110345001-001
Left posterior inferior parietal cortex causally supports the retrieval of action knowledge. - In: NeuroImage, ISSN 1095-9572, Bd. 219 (2020), 117041, insges. 11 S.
Conceptual knowledge is central to human cognition. The left posterior inferior parietal lobe (pIPL) is implicated by neuroimaging studies as a multimodal hub representing conceptual knowledge related to various perceptual-motor modalities. However, the causal role of left pIPL in conceptual processing remains unclear. Here, we transiently disrupted left pIPL function with transcranial magnetic stimulation (TMS) to probe its causal relevance for the retrieval of action and sound knowledge. We compared effective TMS over left pIPL with sham TMS, while healthy participants performed three different tasks - lexical decision, action judgment, and sound judgment - on words with a high or low association to actions and sounds. We found that pIPL-TMS selectively impaired action judgments on low sound-low action words. For the first time, we directly related computational simulations of the TMS-induced electrical field to behavioral performance, which revealed that stronger stimulation of left pIPL is associated with worse performance for action but not sound judgments. These results indicate that left pIPL causally supports conceptual processing when action knowledge is task-relevant and cannot be compensated by sound knowledge. Our findings suggest that left pIPL is specialized for the retrieval of action knowledge, challenging the view of left pIPL as a multimodal conceptual hub.
https://doi.org/10.1016/j.neuroimage.2020.117041
Ag-nanoparticles-decorated Ge-nanowhisker grafted on carbon fiber cloth as flexible and effective SERS substrates. - In: ChemistrySelect, ISSN 2365-6549, Bd. 5 (2020), 27, S. 8338-8343
Three-dimensional (3D) flexible surface enhanced Raman scattering (SERS) substrates of silver nanoparticles (Ag-NPs) decorated Germanium nanowhiskers (Ge-NWHKs) grafted on carbon fiber cloth (CFC) (denoted as Ag-NPsGe-NWHKs@CFC) are constructed via chemical vapor deposition growth of high-density Ge-NWHKs on CFC and then assembly of Ag-NPs on the Ge-NWHKs by galvanic displacement. Ordered 3D framework of Ge-NWHKs grafted flexible CFC impels the formation of large amounts of Ag-NPs with homogenous distribution via spontaneous reduction of Ag+ ions. Thus, the Ag-NPs@Ge-NWHKs@CFC SERS substrates present ultra-high sensitivity, good reproducibility, and high flexibility. This SERS sensor has achieved a detection limit of 1 pM for Rhodamine 6G and 0.1 nM for thiram respectively. The as-fabricated SERS substrates show promising potential for applications in rapid detection of trace organic pollutants in the aquatic environment.
https://doi.org/10.1002/slct.202001290
Grundlegende Untersuchungen zur Entwicklung von fünfachsigen Nanopositioniermaschinen für Mess- und Fertigungszwecke. - In: Jahrbuch Optik und Feinmechanik, ISSN 0075-272X, Bd. 66 (2020), S. 67-92
Sintered porous glasses hosting luminescent species of different nature: Eu3+ ions and Tb3+-doped Ba2TiSi2O8 glass-ceramic powder. - In: Journal of non-crystalline solids, ISSN 0022-3093, Bd. 531 (2020), 119846
Im Titel sind "3+" hochgestellt, "2" und "8" tiefgestellt
We report on the employment of a nano-porous Vycor-type glass as host for two luminescent substances of very different physical and chemical nature, which share the same porous space. Firstly, BTS:Tb^3+ glass-ceramic nano-powders were infiltrated in the porous structure and secondly Eu^3+ ions from a nitrate aqueous solution were included afterwards. Upon sintering, the porous silica matrix collapses, embedding both luminescent species. We focused on the micro and nano-structure of the sintered glasses. Upon sintering a europium silicate phase crystallizes as monocrystalline hexagonal nano-rods, which coexist with amorphous round particles below 100 nm enriched in Eu and Si. Both kinds of particles are embedded in a cristobalite matrix. The interesting microstructure is reported for the first time. The sintering heating rate influences the microstructure after the sintering. The microstructure was investigated by a last generation TEM microscope with aberration correction, EDXS and an exhaustive electron diffraction analysis. The inclusion of BTS:Tb^3+ is only limited, and thus, the its role in the optical properties of the final material is negligible. Luminescence upon UV excitation shows the characteristic emission peaks of Eu^3+. This work highlights the possibility of combining several luminescent materials inside a silica matrix.
https://doi.org/10.1016/j.jnoncrysol.2019.119846
Crystallization of BaF2 from droplets of phase separated glass - evidence of a core-shell structure by ASAXS. - In: CrystEngComm, ISSN 1466-8033, Bd. 22 (2020), 30, S. 5031-5039
Im Titel ist "2" tiefgestellt
https://doi.org/10.1039/C9CE02003A