Zeitschriftenaufsätze ab 2018

Anzahl der Treffer: 1635
Erstellt: Mon, 29 Apr 2024 20:37:54 +0200 in 0.0782 sec


Zavodovskiy, Danylo O.; Bulgakova, Nataliya V.; Sokolowska, Inna; Prylutskyy, Yuriy I.; Ritter, Uwe; Gonchar, Olga O.; Kostyukov, Alexander I.; Vlasenko, Oleh V.; Butowska, Kamila; Borowik, Agnieszka; Piosik, Jacek; Maznychenko, Andriy
Water-soluble pristine C60 fullerenes attenuate isometric muscle force reduction in a rat acute inflammatory pain model. - In: BMC musculoskeletal disorders, ISSN 1471-2474, Bd. 24 (2023), 606, S. 1-8

Background: Being a scavenger of free radicals, C60 fullerenes can influence on the physiological processes in skeletal muscles, however, the effect of such carbon nanoparticles on muscle contractility under acute muscle inflammation remains unclear. Thus, the aim of the study was to reveal the effect of the C60 fullerene aqueous solution (C60FAS) on the muscle contractile properties under acute inflammatory pain. Methods: To induce inflammation a 2.5% formalin solution was injected into the rat triceps surae (TS) muscle. High-frequency electrical stimulation has been used to induce tetanic muscle contraction. A linear motor under servo-control with embedded semi-conductor strain gauge resistors was used to measure the muscle tension. Results: In response to formalin administration, the strength of TS muscle contractions in untreated animals was recorded at 23% of control values, whereas the muscle tension in the C60FAS-treated rats reached 48%. Thus, the treated muscle could generate 2-fold more muscle strength than the muscle in untreated rats. Conclusions: The attenuation of muscle contraction force reduction caused by preliminary injection of C60FAS is presumably associated with a decrease in the concentration of free radicals in the inflamed muscle tissue, which leads to a decrease in the intensity of nociceptive information transmission from the inflamed muscle to the CNS and thereby promotes the improvement of the functional state of the skeletal muscle.



https://doi.org/10.1186/s12891-023-06719-w
Andrada, Emanuel; Hildebrandt, Gregor; Witte, Hartmut; Fischer, Martin S.
Positioning of pivot points in quadrupedal locomotion: limbs global dynamics in four different dog breeds. - In: Frontiers in Bioengineering and Biotechnology, ISSN 2296-4185, Bd. 11 (2023), 1193177, S. 1-16

Dogs (Canis familiaris) prefer the walk at lower speeds and the more economical trot at speeds ranging from 0.5 Fr up to 3 Fr. Important works have helped to understand these gaits at the levels of the center of mass, joint mechanics, and muscular control. However, less is known about the global dynamics for limbs and if these are gait or breed-specific. For walk and trot, we analyzed dogs’ global dynamics, based on motion capture and single leg kinetic data, recorded from treadmill locomotion of French Bulldog (N = 4), Whippet (N = 5), Malinois (N = 4), and Beagle (N = 5). Dogs’ pelvic and thoracic axial leg functions combined compliance with leg lengthening. Thoracic limbs were stiffer than the pelvic limbs and absorbed energy in the scapulothoracic joint. Dogs’ ground reaction forces (GRF) formed two virtual pivot points (VPP) during walk and trot each. One emerged for the thoracic (fore) limbs (VPPTL) and is roughly located above and caudally to the scapulothoracic joint. The second is located roughly above and cranially to the hip joint (VPPPL). The positions of VPPs and the patterns of the limbs’ axial and tangential projections of the GRF were gaits but not always breeds-related. When they existed, breed-related changes were mainly exposed by the French Bulldog. During trot, positions of the VPPs tended to be closer to the hip joint or the scapulothoracic joint, and variability between and within breeds lessened compared to walk. In some dogs, VPPPL was located below the pelvis during trot. Further analyses revealed that leg length and not breed may better explain differences in the vertical position of VPPTL or the horizontal position of VPPPL. The vertical position of VPPPL was only influenced by gait, while the horizontal position of VPPTL was not breed or gait-related. Accordingly, torque profiles in the scapulothoracic joint were likely between breeds while hip torque profiles were size-related. In dogs, gait and leg length are likely the main VPPs positions’ predictors. Thus, variations of VPP positions may follow a reduction of limb work. Stability issues need to be addressed in further studies.



https://www.frontiersin.org/articles/10.3389/fbioe.2023.1193177
Hu, Ping; Dong, Yulian; Wu, Zhijun; Fu, Qun; Zhao, Huaping; Lei, Yong
Bimetallic-based composites for potassium-ion storage: challenges and perspectives. - In: Inorganic chemistry frontiers, ISSN 2052-1553, Bd. 10 (2023), 16, S. 4668-4694

Potassium ion batteries (PIBs) are important for the development of energy storage systems as an effective complement to lithium ion batteries (LIBs) owing to the abundance of potassium resources in the earth's crust to meet the needs of large-scale energy storage systems. To this end, numerous studies have focused on anode materials, which can provide high capacity for PIBs. Bimetallic-based compounds (ABXs) achieve higher capacity and structural diversity due to their different chemical compositions and rich spatial structures. Moreover, the synergistic effect of the two metals makes the structure of ABXs more stable. Hence, ABXs are one of the most promising anode materials. This review focuses on performance optimization strategies (such as metal base selection, structural design, voltage regulation, and electrolyte optimization) and the electrochemical properties of ABXs. Finally, the current challenges and research prospectives of ABXs are presented. This review is expected to provide new perspectives and deeper insights into the study of ABXs as anode materials for PIBs and large-scale energy storage devices.



https://doi.org/10.1039/D3QI00585B
Xu, Dongbo; Zhang, Song; Yu, Yangfei; Zhang, Shu; Ding, Qijia; Lei, Yong; Shi, Weidong
Ultrathin metal Ni layer on ZnO/TiO2 photoelectrodes with excellent photoeletrochemical performance in multiple electrolyte solutions. - In: Fuel, ISSN 1873-7153, Bd. 351 (2023), 128774

It is well known that the oxygen vacancy (Ovac) as the electron-donor dopant in semiconductor can increase the electron-holes separation in photoeletrochemical (PEC) water splitting. Furthermore, the metal Ni can promote the hydrogen evolution reaction (HER) on the surface of semiconductor. In this paper, the ZnO/TiO2 photoelectrodes with rich Ovac was synthesized by electrostatic adsorption through using ZIF-8 as the precursor. Then the ultrathin Ni layer with about 7 nm was deposited on the surface of ZnO/TiO2 (Ni/ZnO/TiO2) by vacuum thermal evaporation method. The Ni/ZnO/TiO2 photoelectrodes showed the highest photocurrent than ZnO/TiO2, Ni/ TiO2 and pure TiO2 photoelectrodes. The durability of Ni/ZnO/TiO2 photoelectrodes was keeping for 10 h in multiple electrolyte solutions under AM 1.5 G illumination and the photocurrent decline can be ignored. The UV-vis absorption spectra demonstrated that the ultrathin Ni layer showed plasma with ZnO/TiO2 for enhancing the water splitting performance. Furthermore, the ultrathin Ni layer enhanced the photogenerated charges transfer for improving the PEC performance. This work provides a new method for ultrathin metal Ni layer with Ovac semiconductor photoelectrode to improve the PEC performance in multiple electrolyte solutions.



https://doi.org/10.1016/j.fuel.2023.128774
Ramon, Ceon; Graichen, Uwe; Gargiulo, Paolo; Zanow, Frank; Knösche, Thomas R.; Haueisen, Jens
Spatiotemporal phase slip patterns for visual evoked potentials, covert object naming tasks, and insight moments extracted from 256 channel EEG recordings. - In: Frontiers in integrative neuroscience, ISSN 1662-5145, Bd. 17 (2023), 1087976, S. 01-20

Phase slips arise from state transitions of the coordinated activity of cortical neurons which can be extracted from the EEG data. The phase slip rates (PSRs) were studied from the high-density (256 channel) EEG data, sampled at 16.384 kHz, of five adult subjects during covert visual object naming tasks. Artifact-free data from 29 trials were averaged for each subject. The analysis was performed to look for phase slips in the theta (4-7 Hz), alpha (7-12 Hz), beta (12-30 Hz), and low gamma (30-49 Hz) bands. The phase was calculated with the Hilbert transform, then unwrapped and detrended to look for phase slip rates in a 1.0 ms wide stepping window with a step size of 0.06 ms. The spatiotemporal plots of the PSRs were made by using a montage layout of 256 equidistant electrode positions. The spatiotemporal profiles of EEG and PSRs during the stimulus and the first second of the post-stimulus period were examined in detail to study the visual evoked potentials and different stages of visual object recognition in the visual, language, and memory areas. It was found that the activity areas of PSRs were different as compared with EEG activity areas during the stimulus and post-stimulus periods. Different stages of the insight moments during the covert object naming tasks were examined from PSRs and it was found to be about 512 ± 21 ms for the ‘Eureka’ moment. Overall, these results indicate that information about the cortical phase transitions can be derived from the measured EEG data and can be used in a complementary fashion to study the cognitive behavior of the brain.



https://doi.org/10.3389/fnint.2023.1087976
Heitmar, Rebekka; Link, Dietmar; Kotliar, Konstantin; Schmidl Doreen Silvia; Klee, Sascha
Editorial: Functional assessments of the ocular circulation. - In: Frontiers in medicine, ISSN 2296-858X, Bd. 10 (2023), 1222022, S. 01-04

https://doi.org/10.3389/fmed.2023.1222022
Otto, Henning; Naumann, Clemens; Odenthal, Christian; Cierpka, Christian
Unsteady inherent convective mixing in thermal-energy-storage systems during standby periods. - In: PRX energy, Bd. 2 (2023), 4, 043001, S. 043001-1-043001-17

Recent studies on the flow phenomena in stratified thermal-energy-storage (TES) systems have shown that heat conduction from the hot upper fluid layer through the vertical tank sidewall into the lower cold fluid layer leads to counterdirected wall jets adjacent to the vertical sidewalls. It was shown that these phenomena destroyed half of the total exergy content in less than a tenth of the storage time constant of a 2-m3 stratified TES system. This paper investigates short-term fluctuations of the wall jets since these fluctuations can potentially mix the hot and cold zones of the thermal stratification that are separated by the thermocline region. Using particle-image velocimetry measurements in two regions of a TES model experiment (near-wall region and far-field region) and analyzing the frequency content of the velocity fields revealed characteristic oscillations for different regions. In the near-wall region, observed fluctuations agreed well with an adjusted boundary layer frequency from the literature, showing that the wall jet is transitioning from laminar to turbulent flow. In the far-field region, the oscillations are related to the Brunt-Väisälä frequency. It is shown that the fluctuations from the boundaries of the thermocline region are most dominant and propagate into deeper regions of the thermocline. A comparison to data from the large-scale test facility for thermal energy storage in molten salt at the German Aerospace Center in Cologne showed good agreement. The consensus between the two experiments proves firstly that a small-scale model experiment with water as a storage liquid can be used to analyze the physical phenomena of large-scale molten salt storage facilities and secondly that these fluctuations are relevant for exergy destruction in real-scale TES.



https://doi.org/10.1103/PRXEnergy.2.043001
Zeußel, Lisa; Schober, Andreas; Ullmann, Fabian; Krischok, Stefan; Heinrich, Doris; Singh, Sukhdeep
Visible-light-assisted donor-acceptor-Stenhouse-adduct-based reversible photoswitching on a laser-structurable OrmoComp substrate. - In: ACS applied polymer materials, ISSN 2637-6105, Bd. 5 (2023), 10, S. 8631-8640

Laser-assisted nanolithography of commercially available photoresists is offering a limitless designing opportunity in the micro- and nanostructuring of 3D organotypic cell culture scaffolds. Among them, chemically functionalized OrmoComp has shown promising improvement in cell adhesion that paves the way to assemble cellular entities on a desirable geometry. Establishing a photoswitchable chemistry on the OrmoComp surface may offer an additional degree of freedom to manipulate the surface chemistry locally and selectively. We have established the methods for functionalization of the photopolymerized OrmoComp surface with visible-light-switchable donor-acceptor Stenhouse adducts. Unlike other polymers, a photopolymerized OrmoComp surface appears to be optimal for reversible photothermal switching, offering the possibility to influence surface properties like absorption and hydrophilicity tremendously. Light-assisted chemical modulation between colored triene-2-ol and colorless cyclopentenone can be achieved to a size region as narrow as 20 μm. Thermal reversion to the original triene-2-ol state can be analyzed spectroscopically and observed with the naked eye.



https://doi.org/10.1021/acsapm.3c01766
Sachs, Sebastian; Schmidt, Hagen; Cierpka, Christian; König, Jörg
On the behavior of prolate spheroids in a standing surface acoustic wave field. - In: Microfluidics and nanofluidics, ISSN 1613-4990, Bd. 27 (2023), 12, 81, S. 1-19

The active manipulation of particle and cell trajectories in fluids by high-frequency standing surface acoustic waves (sSAW) allows to separate particles and cells systematically depending on their size and acoustic contrast. However, process technologies and biomedical applications usually operate with non-spherical particles, for which the prediction of acoustic forces is highly challenging and remains a subject of ongoing research. In this study, the dynamical behavior of prolate spheroids exposed to a three-dimensional acoustic field with multiple pressure nodes along the channel width is examined. Optical measurements reveal an alignment of the particles orthogonal to the pressure nodes of the sSAW, which has not been reported in literature so far. The dynamical behavior of the particles is analyzed under controlled initial conditions for various motion patterns by imposing a phase shift on the sSAW. To gain detailed understanding of the particle dynamics, a three-dimensional numerical model is developed to predict the acoustic force and torque acting on a prolate spheroid. Considering the acoustically induced streaming around the particle, the numerical results are in excellent agreement with experimental findings. Using the proposed numerical model, a dependence of the acoustic force on the particle shape is found in relation to the acoustic impedance of the channel ceiling. Hence, the numerical model presented herein promises high progress for the design of separation devices utilizing sSAW, exploiting an additional separation criterion based on the particle shape.



https://doi.org/10.1007/s10404-023-02690-z
Sayeed, Akbar; Guven, Damla; Döbereiner, Michael; Semper, Sebastian; Gentile, Camillo; Bodi, Anuraag; Cheng, Zihang
A framework for developing and evaluating algorithms for estimating multipath propagation parameters from channel sounder measurements. - In: IEEE transactions on wireless communications, Bd. 0 (2023), 0, S. 1-16

A framework is proposed for developing and evaluating algorithms for extracting multipath propagation components (MPCs) from measurements collected by channel sounders at millimeter-wave frequencies. Sounders equipped with an omni-directional transmitter and a receiver with a uniform planar array (UPA) are considered. An accurate mathematical model is developed for the spatial frequency response of the sounder that incorporates the non-ideal cross-polar beampatterns for the UPA elements. Due to the limited Field-of-View (FoV) of each element, the model is extended to accommodate multi-FoV measurements in distinct azimuth directions. A beamspace representation of the spatial frequency response is leveraged to develop three progressively complex algorithms aimed at solving the single-snapshot maximum likelihood estimation problem: greedy matching pursuit (CLEAN), space-alternative generalized expectation-maximization (SAGE), and RiMAX. The first two are based on purely specular MPCs whereas RiMAX also accommodates diffuse MPCs. Two approaches for performance evaluation are proposed, one with knowledge of ground truth parameters, and one based on reconstruction mean-squared error. The three algorithms are compared through a demanding channel model with hundreds of MPCs and through real measurements. The results demonstrate that CLEAN gives quite reasonable estimates which are improved by SAGE and RiMAX. Lessons learned and directions for future research are discussed.



https://doi.org/10.1109/TWC.2023.3318532